Polyetheramine Detergent Composition for Cold-Water Grease Removal

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Solution Overview

Problem

Current laundry detergents are ineffective at removing grease stains at low wash temperatures, such as 30°C or below, without compromising the quality or production of detergents.

Innovation Solution

A cleaning composition containing 1% to 70% surfactant and 0.1% to 10% polyetheramine, specifically formulated to enhance grease removal in cold water, comprising polyetheramines derived from reacting a 1,3-diol with alkylene oxide and subsequent amination or reductive cyanoethylation, which are added to the detergent to improve cleaning performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional surfactants are used in cold water washing, then detergent production and quality are maintained, but grease stain removal effectiveness deteriorates

Engineering Contradiction:
Improvedetergent qualityVSAvoidgrease removal effectiveness
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent combines conventional surfactants with polyetheramine compounds to create a composite detergent system. The polyetheramine (specifically those with molecular weights of 100-1000 g/mol and specific structural formulas) works synergistically with surfactants to enhance grease removal at low temperatures while maintaining detergent quality and production processes

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention changes the chemical composition parameters of the detergent by introducing polyetheramine compounds with specific molecular weight ranges (100-1000 g/mol) and structural characteristics (formulas I and II with specific R groups and amination degrees). This parameter modification enables effective grease removal at cold temperatures without compromising detergent quality

Inventive Principle:
Principle #35Parameter changes

2Productivity

If aliphatic amine compounds are added to improve low-temperature cleaning, then grease removal is enhanced, but particulate cleaning performance deteriorates

Engineering Contradiction:
Improvecold water grease cleaningVSAvoidparticulate cleaning
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies local quality by using polyetheramine compounds with specific localized structural features (formulas I and II with particular R group configurations and amination degrees of 10-50%). This targeted molecular structure provides grease removal enhancement at specific locations (grease-stained areas) without adversely affecting overall particulate cleaning performance

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention precisely controls the molecular weight parameter (100-1000 g/mol) and structural parameters (formulas I and II with specific R groups and amination degrees) of the polyetheramine to achieve selective enhancement of grease removal while maintaining balanced particulate cleaning capability

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively removes grease stains in cold water without affecting the quality of the detergents, providing improved cleaning performance at low temperatures without adverse effects on particulate cleaning.

Implementation Method 1

The cleaning composition comprises from about 1% to about 70% by weight of a surfactant and from about 0.1% to about 10% by weight of a polyetheramine

Methodology Applied
Scientific EffectSurfactant: Surfactant

Data Source

PatentEP3197988B1Cleaning compositions containing a polyetheramine
Publication Date: 2018.08.01 PROCTER & GAMBLE CO
  • EP3197988B1 patent drawing
  • EP3197988B1 patent drawing
  • EP3197988B1 patent drawing

AI summary

The present invention relates generally to cleaning compositions and, more specifically, to cleaning compositions containing a polyetheramine that is suitable for removal of stains from soiled materials. A cleaning composition comprises from 1% to 70% by weight of a surfactant; and from 0.1% to 10% of a polyetheramine of Formula (I), Formula (II), a mixture thereof. wherein each of R1 -R12 is independently selected from H, alkyl, cycloalkyl, aryl, alkylaryl, or arylalkyl, wherein at least one of R1 - R6 and at least one of R7 -R12 is different from H, each of A1 -A9 is independently selected from linear or branched alkylenes having 2 to 18 carbon atoms, each of Z1 -Z4 is independently selected from OH, CH2 CH2 CH2 NH2, NH2, NHR', or NR'R", where the degree of amination is less than 50%, where R' and R" are independently selected from alkylenes having 2 to 6 carbon atoms, wherein the sum of x+y is in the range of 2 to 200, wherein x>l and y≥l, and the sum of x1 + y1 is in the range of 2 to 200, wherein X1> = 1 and y1 > = 1.