Polyetheramine Grease Removal in Cold Water Detergents

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Solution Overview

Problem

Current laundry detergents fail to achieve satisfactory cleaning performance at low wash temperatures, particularly in removing grease stains in cold water without affecting the quality or production of detergents.

Innovation Solution

A cleaning composition containing 1% to 70% surfactant system and 0.1% to 10% polyetheramine, specifically formulated to enhance grease removal in cold water, comprising polyetheramines obtained by reacting a dialcohol with C2-C4 alkylene oxide and subsequent amination, which effectively removes grease stains without interfering with detergent quality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional surfactants and known additives (aliphatic amines, linear alkoxypropylamines) are used in laundry detergents, then detergent power is enhanced for grease removal, but satisfactory cleaning performance at low temperatures (30°C and below) cannot be achieved

Engineering Contradiction:
Improvecleaning performance at low temperatureVSAvoiddetergent effectiveness
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent introduces a novel polyetheramine compound with specific molecular structure parameters (molecular weight 200-1000, specific formula I structure) that changes the chemical parameters of the detergent system, enabling effective grease removal at low temperatures where conventional additives fail

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite detergent formulation combining conventional surfactants with the novel polyetheramine compound (0.1-10% by weight), where the composite system achieves synergistic effects that enable low-temperature cleaning performance without compromising overall detergent quality

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If high-molecular-weight branched trifunctional primary amines (e.g., Jeffamine T-5000) are used to suppress suds, then suds suppression is achieved, but grease removal performance at cold temperatures is not improved

Engineering Contradiction:
Improvesuds suppressionVSAvoidcold water grease cleaning
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent changes the molecular weight parameter from high (≥1000) to low (200-1000), and modifies the structural parameters to follow formula I, creating a polyetheramine that provides both cold water grease cleaning effectiveness and controlled sudsing properties, eliminating the need to choose between these opposing functions

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If low molecular weight organic diamines are used in detergent compositions, then hand dishwashing applications are improved, but laundry detergent grease removal at low temperatures remains insufficient

Engineering Contradiction:
Improvehand dishwashing performanceVSAvoidlaundry grease removal at low temperature
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent applies the principle of local quality by designing a polyetheramine with specific local structural features (formula I with particular R1, R2, R3, R4 groups and A1-A6 alkylene chains) that are optimized for laundry grease removal, distinguishing it from the diamines optimized for dishwashing applications

Inventive Principle:
Principle #3Local quality

Data Source

PatentEP3122849B1Cleaning compositions containing a polyetheramine
Publication Date: 2021.07.21 PROCTER & GAMBLE CO
  • EP3122849B1 patent drawing
  • EP3122849B1 patent drawing
  • EP3122849B1 patent drawing

AI summary

The present invention relates generally to cleaning compositions and, more specifically, to cleaning compositions containing a polyetheramine that is suitable for removal of stains from soiled materials.