Polyetheramine Friction Modifier for Engine Lubrication

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Solution Overview

Problem

Current friction modifiers, such as glycerol monooleate, do not adequately reduce friction between engine parts, leading to energy losses and decreased fuel efficiency in internal combustion engines, despite their other benefits.

Innovation Solution

A non-aqueous lubricant composition is developed using an organic friction modifier formed from the reaction of polyisobutylene succinic anhydride and a hydrophilic polyetheramine, which significantly reduces boundary and thin-film friction when used in engine lubrication.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If traditional friction modifiers such as glycerol monooleate are used, then other benefits are achieved, but friction between engine parts is not adequately reduced

Engineering Contradiction:
Improvefriction lossVSAvoidfriction reduction effectiveness
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent modifies the chemical structure of friction modifiers by changing parameters such as molecular weight, degree of etherification, and amine functionality. The friction modifier comprises a polyetheramine with specific structural parameters (ether oxygen content, amine group functionality) that are optimized to reduce friction while maintaining stability in non-aqueous lubricant compositions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite friction modifier molecules that combine multiple functional groups within a single molecular structure. The polyetheramine contains both ether oxygen atoms for lubricity and amine groups for friction reduction, creating a composite molecular structure that addresses multiple requirements simultaneously.

Inventive Principle:
Principle #40Composite materials

2Reliability

If additives such as zinc dialkyl dithio phosphate are used to protect engine parts, then protection is achieved, but thin-film friction increases

Engineering Contradiction:
Improveengine part protectionVSAvoidthin-film friction
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The polyetheramine friction modifier acts as an intermediary substance that forms a protective film between moving surfaces, reducing direct metal-to-metal contact. The molecule mediates between the need for surface protection and the need for low friction by providing both adhesive and lubricating properties in the boundary and thin-film lubrication regimes.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the chemical parameters of the friction modifier to achieve optimal performance. The polyetheramine has specific molecular weight ranges, ether oxygen contents (2-20 moles per mole of amine), and amine functionalities that are optimized to provide protection without excessive friction increase.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition exhibits lower friction properties than traditional lubricants, thereby enhancing fuel economy and reducing energy losses in engines by effectively lubricating sliding parts.

Implementation Method 1

engine oils play an important role in lubricating a variety of sliding parts in the engine

Methodology Applied
Scientific EffectLubrication: Lubrication

Implementation Method 2

valve systems and top and bottom dead centers of pistons are likely to be in a state of boundary and/or thin-film lubrication

Methodology Applied
Scientific EffectBoundary lubrication:

Implementation Method 3

Thin-film friction is the friction generated by a fluid, such as a lubricant, moving between two surfaces when the distance between the two surfaces is very small

Methodology Applied
Scientific EffectThin-film friction:

Data Source

PatentEP3265546B1Novel organic friction modifiers
Publication Date: 2021.12.29 HUNTSMAN PETROCHEMICAL LLC
  • EP3265546B1 patent drawing
  • EP3265546B1 patent drawing
  • EP3265546B1 patent drawing

AI summary

The present disclosure relates to novel organic friction modifiers for use in non-aqueous lubricant compositions, the organic friction modifiers comprising a product formed from the reaction of polyisobutylene succinic anhydride and a hydrophilic polyetheramine.