Polyetheramine Salts for Cold Water Detergent Cleaning

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Solution Overview

Problem

Current laundry detergents fail to achieve satisfactory cleaning at low temperatures, particularly in cold water, and there is a need for a detergent additive that can improve grease removal without affecting production or quality.

Innovation Solution

A detergent composition containing a salt of a polyetheramine and a polymeric acid, where the polyetheramine contains at least two propylene oxide units and/or butylene oxide units, and the polymeric acid is a homopolymer of carboxylic acid or a copolymer of acrylic and maleic acid, formulated as a powder or granule to enhance cleaning performance at low temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional surfactants and known additives are used in detergent compositions, then the detergent can be manufactured and shipped, but it fails to achieve satisfactory cleaning performance at low temperatures (30°C and below)

Engineering Contradiction:
Improvecleaning performance at low temperatureVSAvoidtemperature range effectiveness
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent changes the chemical parameters of the detergent composition by incorporating polyetheramine salts with specific molecular weights (100-10,000) and particular structural characteristics (containing ethylene oxide and/or propylene oxide units). These parameter changes enable the detergent to maintain effective cleaning performance across a broad temperature range, specifically achieving satisfactory results at low temperatures (30°C and below) while preserving hot water wash effectiveness.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If liquid polyetheramines are used to improve cold water cleaning, then cleaning performance improves, but shipping and storage become more difficult and production becomes more complex

Engineering Contradiction:
Improvecold water grease cleaningVSAvoidproduction and shipping of solid detergent
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies phase transition by converting the polyetheramine from liquid form to solid form through salt formation with carboxylic acids. The polyetheramine salt exhibits a melting point of 50°C or higher, enabling it to be incorporated into solid detergent compositions (powders, granules, tablets) while retaining the cold water cleaning effectiveness of the original liquid polyetheramine. This phase change resolves the contradiction between improving cold water cleaning and maintaining ease of manufacture and shipping.

Inventive Principle:
Principle #36Phase transitions

3Ease of manufacture

If polyetheramine salts with low melting points are used, then they are easier to incorporate into detergent formulations, but they cannot form stable solid detergent compositions for shipping

Engineering Contradiction:
Improveincorporation into detergent formulationVSAvoidsolid detergent composition stability
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The patent specifies particular parameter ranges for the polyetheramine salt to resolve this contradiction: molecular weight of 100-10,000, containing 2-50 ethylene oxide units and 2-50 propylene oxide units per molecule, and forming salts with carboxylic acids having 1-20 carbon atoms. These parameter changes ensure the salt has a melting point of 50°C or higher, enabling stable solid detergent compositions while remaining manufacturable.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The detergent composition effectively improves grease removal in cold water while simplifying the production and shipping of solid detergents, maintaining the quality and performance of laundry detergents.

Implementation Method 1

laundry detergents containing an aliphatic amine compound, in addition to at least one synthetic anionic and/or nonionic surfactant

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Implementation Method 2

improve the removal of grease stains at temperatures of 30°C and below

Methodology Applied
Scientific EffectEmulsification: Emulsion

Implementation Method 3

reaction of diamines or polyamines with alkylene oxides and compounds derived from the reaction of amine terminated polyethers with epoxide functional compounds

Methodology Applied
Scientific EffectAcid-base reaction: Chemical Bonding

Implementation Method 4

A polyetheramine in the form of a powder or a granule may render the shipping of such material easier

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentEP3212753B1Detergent compositions containing salts of polyetheramines and polymeric acid
Publication Date: 2019.07.31 PROCTER & GAMBLE CO
  • EP3212753B1 patent drawing
  • EP3212753B1 patent drawing
  • EP3212753B1 patent drawing

AI summary

The present invention relates generally to detergent compositions and, more specifically, to detergent compositions containing salts of polyetheramines and polymeric acid, particularly salts of polyetheramines and polycarboxylic acid, which are suitable for removal of stains from soiled materials.