Polyetherimide Film Surface Roughness for Capacitor Slidability

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Solution Overview

Problem

Current dielectric films for film capacitors face challenges with heat resistance, slidability, and voltage proof, particularly in high-temperature applications like hybrid cars, where existing resins like PP, PET, PPS, and PEN have limitations in heat resistance, dielectric breakdown voltage, and dielectric loss, and amorphous PEI films lack ductility for biaxial stretching.

Innovation Solution

A method for manufacturing a film with a thermoplastic resin composition, including a polyetherimide resin, using a T-die extrusion process with a cooling roll having a specific rough surface pattern to enhance heat resistance, slidability, and voltage proof, by transferring a uniformly aligned pattern of minute bosses or dents onto the film surface, optimizing surface roughness and dynamic friction coefficient.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If a thermoplastic resin film is used for film capacitors, then heat resistance and dielectric properties are improved, but slidability deteriorates causing manufacturing troubles

Engineering Contradiction:
Improveheat resistanceVSAvoidslidability
Core Design Contradiction:
TemperatureVSEase of operation

Solution Approach 1:

The invention applies a roughening treatment only to the surface layer of the film while maintaining the bulk properties of the thermoplastic resin. This creates a dual-layer structure where the surface has enhanced slidability through controlled roughness (Ra: 0.03-0.5 μm) while the interior maintains the heat resistance and dielectric properties of the original thermoplastic resin composition.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention creates a composite structure by combining a thermoplastic resin base material with a surface layer having specific roughness characteristics. The surface layer is formed by dispersing inorganic particles or applying a coating that creates the desired roughness profile, resulting in a composite material that exhibits both improved slidability and retained thermal properties.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If the film surface is roughened to improve slidability, then manufacturing operation is improved, but dielectric breakdown voltage deteriorates

Engineering Contradiction:
ImproveslidabilityVSAvoiddielectric breakdown voltage
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The invention precisely controls the surface roughness parameters, specifically maintaining Ra within 0.03-0.5 μm and Rz within 0.06-1.0 μm. This parameter optimization ensures that the surface is rough enough to provide slidability during manufacturing but not so rough as to create defects that would compromise dielectric breakdown voltage. The controlled roughness prevents excessive stress concentration while maintaining operational ease.

Inventive Principle:
Principle #35Parameter changes

3Temperature

If amorphous PEI resin is used to achieve high heat resistance, then temperature resistance is improved, but ductility deteriorates preventing biaxial stretching

Engineering Contradiction:
Improveheat resistanceVSAvoidductility
Core Design Contradiction:
TemperatureVSStability of the object's composition

Solution Approach 1:

The invention applies a roughening treatment only to the surface layer of the film while maintaining the bulk properties of the thermoplastic resin. This creates a dual-layer structure where the surface has enhanced slidability through controlled roughness (Ra: 0.03-0.5 μm) while the interior maintains the heat resistance and dielectric properties of the original thermoplastic resin composition.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention creates a composite structure by combining a thermoplastic resin base material with a surface layer having specific roughness characteristics. The surface layer is formed by dispersing inorganic particles or applying a coating that creates the desired roughness profile, resulting in a composite material that exhibits both improved slidability and retained thermal properties.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in a film with improved heat resistance, enhanced productivity, and high voltage proof, addressing the limitations of existing films by achieving excellent slidability and dielectric breakdown voltage, suitable for high-temperature applications without the need for biaxial stretching.

Implementation Method 1

pinching and cooling the film between a pressure roll and a cooling roll having a rough surface, thereby transferring a uniformly aligned pattern of a plurality of minute bosses or dents onto a surface of the film

Methodology Applied
Scientific EffectSurface transfer:

Implementation Method 2

melting and extruding the forming material to a film through a T-die

Methodology Applied
Scientific EffectExtrusion: Extrusion

Data Source

PatentUS8790558B2Method for manufacturing film for film capacitor
Publication Date: 2014.07.29 SHIN ETSU POLYMER CO LTD
  • US8790558B2 patent drawing
  • US8790558B2 patent drawing
  • US8790558B2 patent drawing

AI summary

A film for film capacitors having a thickness of 10 microns or less, is manufactured by the successive steps of: mixing and preparing a forming material composed of a thermoplastic resin composition; melting and extruding the forming material to a film through a T-die; pinching and cooling the film between a pressure roll and a cooling roll having a rough surface for forming a rough surface to the film, wherein the rough surface of the cooling roll has (σ/Ra) of 0.2 or less, and the rough surface of the film has (σ/Ra) of 0.2 or less, where (Ra) is an arithmetic average roughness defined by a method specified in JIS B 0601 2001, and (σ) is a standard deviation; and rolling up the cooled film onto a winding tube in a winding unit.