Polyethylene Blend Fiber Modulus and Softness Trade-off

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Solution Overview

Problem

Ethylene-based polymer fibers used in spunbond nonwoven fabrics lack the necessary modulus and tensile strength to replace polypropylene fibers, particularly in applications requiring enhanced softness and performance like baby diapers, due to their inherent lower mechanical properties.

Innovation Solution

A polymeric blend of 95-99 wt% high density ethylene-based polymer with 1-5 wt% low density ethylene-based polymer, optimizing the molecular weight distribution and melt index to enhance the fiber's modulus and tensile strength while maintaining softness, achieved through specific processing conditions and additives.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If ethylene-based polymer fibers are used to provide enhanced softness, then softness is improved, but modulus and tensile strength deteriorate

Engineering Contradiction:
ImprovesoftnessVSAvoidmodulus and tensile strength
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent creates a composite fiber system by blending high density ethylene-based polymer (95-99 wt%) with low density ethylene-based polymer (1-5 wt%). This composite approach allows the fiber to exhibit enhanced softness from the ethylene-based polymer while the specific composition and molecular weight distribution provide improved modulus and tensile strength, resolving the contradiction between softness and mechanical strength

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes specific parameters including molecular weight distribution (Mw/Mn ratio), melt index, and compositional ratios to achieve the desired balance. By controlling these parameters, the fiber attains both enhanced softness and improved mechanical properties, transforming the trade-off into a optimized performance state

Inventive Principle:
Principle #35Parameter changes

2Strength

If polypropylene fibers are used to achieve high modulus and tensile strength, then strength is improved, but softness deteriorates

Engineering Contradiction:
Improvemodulus and tensile strengthVSAvoidsoftness
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The blended fiber system acts as a composite that combines the advantages of different polymer types. The high density ethylene-based polymer provides the base structure with good mechanical properties, while the low density ethylene-based polymer enhances softness, achieving a balance that neither pure polypropylene nor pure ethylene-based polymer could attain alone

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent creates fibers with specific local properties through controlled blending and processing. The fiber structure is designed to exhibit different characteristics at different scales - high strength at the macro level while maintaining softness at the tactile level, allowing the material to serve multiple functional requirements simultaneously

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS10145027B2Fiber comprising polyethylene blend
Publication Date: 2018.12.04 DOW GLOBAL TECHNOLOGIES LLC
  • US10145027B2 patent drawing
  • US10145027B2 patent drawing
  • US10145027B2 patent drawing

AI summary

The present disclosure is directed to a fiber that is composed of a polymeric blend including (i) 95 wt % to 99 wt % of a high density ethylene-based polymer having a Mw/Mn from 2.0 to 3.0 and (ii) from 5 wt % to 1 wt % of a low density ethylene-based polymer having a melt index from 5 g/10 min to 15 g/10 min. The fiber has a density from 1 denier to 2 denier and a 3% secant modulus from 8.5 g/denier to 20 g/denier.