Alternating Polyethylene Multilayer Film for Interlayer Adhesion

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Solution Overview

Problem

Multilayer film structures face challenges in achieving optimal interfacial compatibility and adhesion between polyethylene layers, affecting overall performance properties such as toughness, optical properties, and curl characteristics.

Innovation Solution

The film structure comprises alternating layers of linear low density polyethylene and high density polyethylene, promoting co-crystallization across interfaces to form a homogenous lattice, with specific density and melt index ranges and the inclusion of nucleating agents to enhance adhesion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If multilayer film structures are used to achieve specific performance properties, then functional characteristics (barrier, sealability, toughness) are improved, but interfacial compatibility and adhesion between layers deteriorate

Engineering Contradiction:
Improveperformance propertiesVSAvoidinterfacial compatibility
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent uses all polyethylene layers with varying densities (LLDPE and HDPE) that are chemically homogeneous but physically differentiated. This allows the layers to be compatible and form strong interfacial adhesion through co-crystallization, while still providing different functional properties through density variations. The homogeneous chemical composition eliminates interfacial incompatibility issues that would arise from using chemically different polymers.

Inventive Principle:
Principle #33Homogeneity

Solution Approach 2:

The patent creates a composite multilayer structure using different polyethylene densities (LLDPE with 0.910-0.940 g/cm³ and HDPE with ≥0.945 g/cm³). Each layer contributes different properties: LLDPE provides toughness and flexibility, while HDPE provides stiffness and barrier properties. The composite structure achieves overall performance optimization by combining these complementary materials with controlled interfacial adhesion.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If multiple polyethylene layers are combined to achieve optimal adhesion, then interlayer compatibility is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveinterlayer adhesionVSAvoidfilm structure complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent divides the film structure into multiple discrete layers (at least five alternating layers) of different polyethylene densities. Each layer is independently formulated with specific density and melt index ranges, allowing precise control of interfacial properties. This segmentation enables optimization of adhesion at each interface while maintaining overall structural manageability through repetitive alternating patterns.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent controls interlayer adhesion by adjusting physical parameters of the polyethylene layers, specifically density (0.910-0.975 g/cm³) and melt index (0.1-10 g/10 min). By varying these parameters within defined ranges, the patent optimizes co-crystallization behavior and interfacial compatibility without changing the fundamental polyethylene chemistry, thereby managing complexity through parameter control rather than material diversity.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If alternating layers of LLDPE and HDPE are used to improve toughness and optical properties, then performance properties are enhanced, but stiffness may deteriorate

Engineering Contradiction:
Improvetoughness and optical propertiesVSAvoidstiffness
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent assigns different functional qualities to different layers: LLDPE layers (with higher elongation and impact resistance) provide toughness and optical clarity, while HDPE layers (with higher crystallinity and modulus) provide stiffness and dimensional stability. This local differentiation of qualities within the multilayer structure allows the film to exhibit both high toughness and adequate stiffness through the synergistic combination of layers with specialized local functions.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Improves the performance properties of the multilayer film structure by enhancing interlayer adhesion, resulting in improved toughness and optical properties while maintaining stiffness.

Implementation Method 1

the interlayer adhesion may be improved by promoting co-crystallization across the interfaces between layers thereby forming a homogenous lattice of interfacial crystals

Methodology Applied
Scientific EffectCo-crystallization: Crystallisation

Implementation Method 2

a high density polyethylene having a density of at least 0.945 g/cm3, a melt index, I2 of from 0.1 to 10 g/10 min and comprising from 0 to 1 weight percent of a nucleating agent or a mixture of nucleating agents

Methodology Applied
Scientific EffectNucleation: Nucleation

Data Source

PatentUS12576613B2Multilayer film structure
Publication Date: 2026.03.17 NOVA CHEM (INT) SA
  • US12576613B2 patent drawing
  • US12576613B2 patent drawing

AI summary

An all polyethylene multilayer film structure having alternating layers of (A) a linear low density polyethylene and (B) a high density polyethylene has improved performance properties relative to a film structure in which the (A) and (B) layers are arranged in a block like or random manner.