Polyethylene Resin Pipe Composition for Ultrapure Water Purity
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Solution Overview
Problem
Conventional pipeline materials for ultrapure water, such as fluorine resins, face challenges in workability and cost, and polyethylene-based resins used in general-purpose pipelines elute calcium into the water, failing to meet stringent quality requirements due to chlorine-containing catalysts and neutralizing agents like calcium stearate.
Innovation Solution
A polyethylene-based resin pipeline member with a controlled calcium concentration between 10 ppm and 60 ppm, combined with a phenol antioxidant, is developed to reduce calcium elution and enhance mechanical properties, ensuring the pipeline meets the required water quality standards for ultrapure water applications.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If fluorine resin is used as pipeline material for ultrapure water, then water quality purity is improved, but workability and cost deteriorate
Solution Approach 1:
The invention changes the chemical composition parameters of the polyethylene resin by controlling catalyst residue content to 50 ppm or less and calcium stearate content to 300 ppm or less, enabling polyethylene to achieve ultrapure water quality standards while maintaining its superior workability and cost advantages over fluorine resins
Solution Approach 2:
The invention replaces expensive fluorine resin with cost-effective polyethylene resin, achieving the same water quality protection function at lower material cost, making pipeline systems more economically viable
2Ease of manufacture
If polyethylene-based resin with chlorine-containing catalyst is used, then workability and cost are improved, but calcium elution into water increases
Solution Approach 1:
The invention strictly controls the calcium stearate content parameter to 300 ppm or less and catalyst residue to 50 ppm or less, fundamentally reducing the source of calcium elution while maintaining polyethylene's manufacturing advantages
Solution Approach 2:
The invention takes preliminary action during resin manufacturing by controlling catalyst neutralization and additive content, preventing excessive calcium elution before the pipeline is installed and used
3Reliability
If calcium stearate is added as neutralizing agent, then catalyst neutralization is improved, but calcium elution into water worsens
Solution Approach 1:
The invention optimizes the calcium stearate content parameter to 300 ppm or less, achieving sufficient catalyst neutralization while minimizing calcium elution into ultrapure water
Solution Approach 2:
The invention implements feedback control by measuring and adjusting calcium stearate content during manufacturing to achieve the optimal balance between catalyst neutralization and calcium elution control
Data Source
AI summary
A pipe (10) includes a polyethylene-based resin layer (21) containing a polyethylene-based resin composition as a major component. The polyethylene-based resin layer (21) forms a pipeline member inner surface (10a). The polyethylene-based resin composition has a calcium concentration of 10 ppm or more and 60 ppm or less.


