Biaxially Oriented Polyethylene Pipe Blends for Uniform Drawing

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Solution Overview

Problem

Producing biaxially oriented polyethylene pipes with uniform thickness is challenging due to high natural draw ratios, which can lead to unbalanced pipes prone to splitting along the axial direction.

Innovation Solution

A process involving the formation of a polyethylene composition comprising high-density polyethylene (HDPE) blended with linear low-density polyethylene (LLDPE) or low-density polyethylene (LDPE), followed by biaxial stretching in the axial and peripheral directions to suppress necking and achieve uniform drawing with a low axial draw ratio.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If high axial draw ratio is used for drawing polyethylene tubes, then the tube can be drawn to achieve uniform thickness, but the pipe becomes highly unbalanced and prone to splitting along the axial direction

Engineering Contradiction:
Improveuniform thicknessVSAvoidprone to splitting
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the material composition parameter by blending HDPE with LLDPE or LDPE in specific ratios (30-70 wt% HDPE, 70-30 wt% LLDPE/LDPE). This compositional parameter change modifies the drawing behavior to achieve uniform thickness at low axial draw ratios (1.2-3.0) while preventing splitting, resolving the contradiction between manufacturing precision and reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite polyethylene material by blending HDPE with LLDPE or LDPE. This composite material combines the high strength properties of HDPE with the excellent drawability and necking suppression of LLDPE/LDPE, enabling uniform drawing at low axial draw ratios without splitting, thus resolving the contradiction between uniform thickness and resistance to splitting

Inventive Principle:
Principle #40Composite materials

2Strength

If HDPE is used alone for pipe production, then the pipe has high strength, but it forms a neck during drawing that must be drawn out to achieve uniform thickness

Engineering Contradiction:
Improvetensile strengthVSAvoidnecking during drawing
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent modifies the material composition parameter by blending HDPE with LLDPE or LDPE in specific ratios. This changes the drawing behavior from necking (pure HDPE) to uniform drawing (blended material), while maintaining adequate strength. The compositional parameter change resolves the contradiction between strength and ease of manufacture

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite polyethylene material that combines HDPE (providing strength) with LLDPE/LDPE (providing uniform drawability and necking suppression). This composite approach resolves the contradiction by integrating the advantageous properties of both material types into a single blend that is both strong and easy to manufacture

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If LLDPE or LDPE is blended with HDPE, then necking is suppressed and uniform drawing with low axial draw ratio is achieved, but the composition becomes more complex

Engineering Contradiction:
Improveuniform drawingVSAvoidcomposition complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent defines specific compositional parameter ranges (30-70 wt% HDPE, 70-30 wt% LLDPE/LDPE) that optimize the blend performance. By establishing these quantitative parameters, the patent simplifies the complexity issue - rather than requiring complex formulation optimization, manufacturers can directly apply the specified ratio ranges to achieve uniform drawing with low axial draw ratios

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent promotes homogeneity in the blend composition by specifying clear weight ratio ranges and using conventional mixing equipment. The blended composition achieves homogeneous distribution of the two polyethylene types, ensuring consistent drawing behavior throughout the material. This homogeneity approach reduces composition complexity by providing a straightforward, uniform blend formulation

Inventive Principle:
Principle #33Homogeneity

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The blending of HDPE with LLDPE or LDPE allows for the production of biaxially oriented pipes with improved hoop tensile strength and uniform thickness, reducing the risk of splitting and enhancing manufacturing stability.

Implementation Method 1

a biaxial orientation of the material may be applied. The biaxial orientation means that the polymer material is oriented in two directions, perpendicular to one another. A pipe can be oriented in the axial direction and peripheral direction (hoop direction) to improve properties such as tensile strength.

Methodology Applied
Scientific EffectBiaxial orientation:

Implementation Method 2

Upon solid-state drawing, semi-crystalline polymers such as polyethylene form a neck, unlike PVC. This neck has to be drawn out until a product with a uniform thickness is obtained. It was found that the blending of the second polyethylene to HDPE leads to suppression of necking, which allows uniform drawing with a low axial draw ratio.

Methodology Applied
Scientific EffectNecking suppression:

Data Source

PatentUS11453157B2Process for producing pipe by biaxial elongation
Publication Date: 2022.09.27 SABIC GLOBAL TECHNOLOGIES BV
  • US11453157B2 patent drawing

AI summary

The invention relates to a process for producing a biaxially oriented pipe by a) forming a polyethylene composition into a tube, wherein the polyethylene composition comprises high density polyethylene (HDPE) and a second polyethylene selected from linear low density polyethylene (LLDPE), low density polyethylene (LDPE) and a combination of LLDPE and LDPE and b) stretching the tube of step a) in the axial direction and peripheral direction to obtain the biaxially oriented pipe.