Polyimide Binder Composition for Low-Temperature Battery Manufacturing

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Solution Overview

Problem

High-temperature heat treatment required for polyimide binders in lithium ion secondary batteries increases manufacturing costs and is undesirable, affecting the cycle characteristics of the batteries.

Innovation Solution

A binder composition comprising polyamic acid and an aromatic compound with an electron donating group and an organic acid group, which allows for the production of polyimide binders at lower temperatures, improving cycle characteristics and reducing manufacturing costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high-temperature heat treatment is used to convert polyamic acid to polyimide binder, then the mechanical strength and cycle characteristics of the battery are improved, but the manufacturing cost increases and the process complexity increases

Engineering Contradiction:
Improvecycle characteristicsVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the chemical composition parameters of the binder system by introducing a polyol component with specific functional groups (carboxyl, hydroxyl, or amine groups) that can react with polyamic acid. This compositional parameter change enables the conversion reaction to proceed at lower temperatures (below conventional curing temperatures), thereby resolving the contradiction between achieving good cycle characteristics and reducing manufacturing cost/process complexity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The polyol component acts as a chemical intermediary that facilitates the conversion of polyamic acid to polyimide at lower temperatures. The polyol's functional groups mediate the reaction process, allowing the transformation to occur under milder heating conditions than conventional methods, thus reducing manufacturing cost while maintaining battery reliability.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Strength

If high-temperature heat treatment is applied to the electrode mixture paste, then the polyimide binder achieves adequate mechanical strength, but the manufacturing equipment requirements increase and production efficiency decreases

Engineering Contradiction:
Improvemechanical strength of binderVSAvoidproduction efficiency
Core Design Contradiction:
StrengthVSProductivity

Solution Approach 1:

By changing the chemical parameters of the binder composition (adding polyol with reactive functional groups), the patent enables the formation of strong polyimide bonds at lower temperatures. This parameter change allows the binding process to be completed more quickly and with less energy, thereby improving production efficiency while maintaining adequate mechanical strength.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the conventional thermal-mechanical curing process (which requires prolonged high-temperature exposure) with a chemical reaction process driven by polyol-polyamic acid interaction. This substitution of the curing mechanism enables bond formation at lower temperatures and shorter times, improving productivity without sacrificing mechanical strength.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Strength

If conventional polyimide binder is used requiring high-temperature treatment, then the binder provides sufficient mechanical properties, but the energy consumption increases

Engineering Contradiction:
Improvebinding strengthVSAvoidenergy consumption
Core Design Contradiction:
StrengthVSUse of energy by moving object

Solution Approach 1:

The patent changes the energy parameter of the curing process by introducing polyol chemistry that enables low-temperature reaction. The functional groups in polyol (carboxyl, hydroxyl, or amine groups) form reactive intermediates with polyamic acid that lower the activation energy required for polyimide formation, thus reducing energy consumption while maintaining binding strength.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the typically harmful effect of requiring high energy input into a benefit by using the polyol's functional groups to create a self-reacting system. The chemical reactivity of polyol functional groups naturally drives the conversion at low temperatures, turning what would be an energy-intensive thermal process into a chemically-driven low-energy process that maintains adequate binding strength.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The binder composition enables excellent cycle characteristics in lithium ion secondary batteries even with lower temperature heat treatment, making it suitable for use in both secondary batteries and other applications like adhesives and molded products.

Implementation Method 1

an aromatic compound comprising an electron donating group and an organic acid group

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS11404694B2Resin composition
Publication Date: 2022.08.02 NEC CORP
  • US11404694B2 patent drawing

AI summary

An object of the present invention is to provide a polyimide binder which can be prepared under lower temperature conditions. The binder composition for a secondary battery of the present invention is characterized in comprising a polyamic acid and an aromatic compound comprising an electron donating group and an organic acid group.