Polyimide-Polysiloxane Composite Substrate for Flexible Displays

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Solution Overview

Problem

Existing polyimide substrates for flexible displays suffer from high coefficient of thermal expansion (CTE), leading to warpage and alignment accuracy issues, and require complex production processes, while current methods for reducing CTE and birefringence limit monomer design freedom and introduce defects during heating.

Innovation Solution

A substrate with a polysiloxane resin layer on a polyimide resin layer, incorporating inorganic oxide particles to reduce CTE and birefringence, allowing for high-definition display manufacturing without complex operations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If a transparent polyimide substrate is used for flexible displays, then flexibility and light transmission are improved, but the coefficient of thermal expansion becomes large causing warpage and alignment accuracy deterioration

Engineering Contradiction:
ImproveflexibilityVSAvoidalignment accuracy
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The patent uses a composite structure consisting of a polyimide resin layer and a polysiloxane resin layer. The polyimide layer provides flexibility and light transmission, while the polysiloxane layer with inorganic oxide particles reduces the coefficient of thermal expansion. This composite material approach allows the substrate to maintain both flexibility and low CTE, preventing warpage and alignment accuracy deterioration during manufacturing and operation.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If the CTE of polyimide substrate is reduced to prevent warpage, then manufacturing precision is improved, but monomer design freedom is limited and defects occur during heating

Engineering Contradiction:
Improvewarpage controlVSAvoidproduction process complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

Instead of modifying the polyimide monomer structure which limits design freedom and causes heating defects, the patent introduces a separate polysiloxane resin layer containing inorganic oxide particles. This composite approach reduces CTE effectively while maintaining the original polyimide composition and manufacturing process, avoiding monomer design constraints and heating-related defects.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The polysiloxane resin layer acts as an intermediary material that mediates the thermal expansion behavior of the substrate. By incorporating inorganic oxide particles into the polysiloxane layer, the overall CTE of the composite substrate is reduced without directly modifying the polyimide resin, thus simplifying the production process and avoiding defects associated with monomer modifications.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If a gas barrier film is formed on polyimide substrate, then protection is improved, but cracks and wrinkles form due to CTE difference between polyimide and silicon oxide/nitride

Engineering Contradiction:
ImproveprotectionVSAvoidfilm integrity
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent creates a composite substrate with polyimide and polysiloxane resin layers where the polysiloxane layer has a CTE intermediate between polyimide and silicon oxide/nitride gas barrier films. This gradient CTE structure reduces the thermal stress difference at interfaces, preventing cracks and wrinkles in the gas barrier film while maintaining protection functionality.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The substrate achieves low CTE, reduced birefringence, and flexibility, enabling high-definition displays with improved processing accuracy and crack resistance, while simplifying production and reducing defects.

Implementation Method 1

the film B contains inorganic oxide particles therein

Methodology Applied
Scientific EffectThermal contraction: Thermal Contraction

Implementation Method 2

incorporating inorganic oxide particles to reduce CTE and birefringence

Methodology Applied
Scientific EffectBirefringence reduction: Birefringence

Data Source

PatentUS10431753B2Substrate for display, color filter using the same and method for the production thereof, organic EL element and method for the production thereof, and flexible organic EL display
Publication Date: 2019.10.01 TORAY INDUSTRIES INC
  • US10431753B2 patent drawing
  • US10431753B2 patent drawing
  • US10431753B2 patent drawing

AI summary

The present invention is a substrate for a display, the substrate having a film B including a polysiloxane resin on at least one surface of a film A including a polyimide resin, wherein the film B contains inorganic oxide particles therein, and the present invention has an object to provide a substrate for a display: being able to be applied to a color filter, an organic EL element, or the like without the need to carry out any complex operations; allowing high-definition displays to be manufactured; and being provided with a low CTE, a low birefringence, and flexibility.