Core-Shell Capsules With Polyisocyanate Shells for Fragrance Control

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Solution Overview

Problem

Existing fragrance formulations face issues with fragrance interactions and premature evaporation, leading to unstable olfactory impressions and sensory properties, necessitating improved microcapsule shell structures for controlled release and stability.

Innovation Solution

A core-shell capsule is developed using a polymeric material formed by reacting linear and/or branched aliphatic polyisocyanates with cyclic aliphatic polyisocyanates and a crosslinking agent, providing a shell structure that balances stability and controlled release of fragrances.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a polymeric shell material is used to enclose fragrance, then stability and prevention of premature evaporation are improved, but controlled release and sensory properties may be compromised

Engineering Contradiction:
ImprovestabilityVSAvoidpremature evaporation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent uses a composite shell structure made from reacting linear/branched aliphatic polyisocyanates with cyclic aliphatic polyisocyanates and crosslinking agents. This composite material provides both stability to prevent premature evaporation and controlled release properties, resolving the contradiction between reliability and harmful factors.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If the shell structure is made more stable to prevent fragrance loss, then fragrance stability is improved, but release control and sensory properties deteriorate

Engineering Contradiction:
Improvefragrance stabilityVSAvoidrelease control
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The patent adjusts the composition parameters of the polymeric material by varying the ratios of linear/branched aliphatic polyisocyanates to cyclic aliphatic polyisocyanates and selecting different crosslinking agents. These parameter changes allow optimization of both fragrance stability and controlled release properties simultaneously.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If existing polyisocyanate-based shells are used, then manufacturing is simplified, but fragrance interactions and evaporation control are insufficient

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidevaporation control
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent employs a composite polymeric material combining linear/branched aliphatic polyisocyanates with cyclic aliphatic polyisocyanates and crosslinking agents. This composite approach maintains ease of manufacture through established polymerization processes while significantly improving evaporation control and preventing fragrance interactions.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The combination of aliphatic polyisocyanates with a crosslinking agent results in a shell that prevents premature fragrance release while maintaining stability, allowing for controlled fragrance release under defined conditions, enhancing sensory properties and stability.

Implementation Method 1

the polymeric material is produced or producible by reacting component (A) with component (B), wherein component (A) comprises or consists of at least one linear aliphatic polyisocyanate and/or at least one branched aliphatic polyisocyanate having more than one isocyanate group, respectively, and at least one cyclic aliphatic polyisocyanate having more than one isocyanate group, and component (B) comprises or consists of one or more crosslinking agent(s)

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Data Source

PatentUS12421480B2Core-shell capsules prepared with linear and cyclic aliphatic polyisocyanates
Publication Date: 2025.09.23 SYMRISE GMBH & CO KG
  • US12421480B2 patent drawing
  • US12421480B2 patent drawing
  • US12421480B2 patent drawing

AI summary

The present invention relates to core-shell capsules prepared with linear and/or branched and cyclic aliphatic polyisocyanates. In particular, the present invention discloses a core-shell capsule, wherein the shell comprises or consists of a polymeric material which is produced or producible by reacting two components, the first component comprising or consisting of at least one linear aliphatic polyisocyanate and/or at least one branched aliphatic polyisocyanate having more than one isocyanate group, respectively, and at least one cyclic aliphatic polyisocyanate having more than one isocyanate group, the second component comprising or consisting of one or more crosslinking agent(s). Furthermore, a product comprising the present core-shell capsule, a process for producing the present core-shell capsules and the use of the present core-shell capsules is provided.