Polylactic acid and polyether compounds

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Solution Overview

Problem

There is a need for improved surfactants with lower foaming properties and enhanced performance for use in personal hygiene products and home care applications, particularly for treating polymeric substrates and nonwoven materials made from bio-based materials like polylactic acid (PLA) and polyethylene (PE), which require effective fibre finishes and cleaning formulations.

Innovation Solution

Development of a polylactic acid and polyether copolymer compound comprising sorbitan ester, fatty alcohol, or fatty acid residues, with multiple lactic acid and oxyethylene groups, which is used as a fibre finish or surfactant, reducing foaming and improving wettability and absorption properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If conventional surfactants are used for treating polymeric substrates, then foaming properties are high, but wettability and absorption performance are insufficient

Engineering Contradiction:
ImprovewettabilityVSAvoidfoaming
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The invention modifies the chemical structure of surfactant molecules by incorporating specific polyether chains with controlled molecular weight and composition, changing the physical and chemical parameters to achieve low foaming while maintaining or improving wettability and absorption performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite surfactant molecules combining hydrophobic groups (for substrate affinity) with hydrophilic polyether chains (for water solubility and low foaming), resulting in a material that simultaneously achieves multiple performance characteristics including reduced foaming and improved wettability

Inventive Principle:
Principle #40Composite materials

2Productivity

If traditional fibre finishes are applied to bio-based polymeric substrates, then processing time is long, but treatment effectiveness is insufficient

Engineering Contradiction:
Improvestrike-through timeVSAvoidtreatment effectiveness
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention optimizes molecular weight, hydrophobic-hydrophilic balance, and chemical composition parameters of the fibre finish compounds to enable faster penetration and binding to polymeric substrates, reducing strike-through time while maintaining treatment effectiveness

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces traditional mechanical/physical finishing methods with chemically-active surfactant compounds that actively interact with the polymeric substrate at molecular level, enabling faster and more effective treatment

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound provides shorter strike-through times, reduced run-off, lower re-wet amounts, and improved wettability, making it suitable for personal hygiene products and effective in low-foaming cleaning formulations, while being environmentally friendly due to its bio-based components.

Implementation Method 1

the compounds according to the invention may surprisingly provide one or more of the following benefits: shorter strike through times, lower run-off amounts, lower re-wet amounts, improved wettability, lower foaming properties, surfactancy properties

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

improved wettability

Methodology Applied
Scientific EffectWetting: Wetting

Data Source

PatentUS20250002647A1Polylactic acid and polyether compounds
Publication Date: 2025.01.02 CRODA INC
  • US20250002647A1 patent drawing

AI summary

Compounds are described which are polylactic acid and polyether copolymers, wherein the compounds comprise: a) at least one of: a sorbitan ester residue, a C6 to C24 fatty alcohol residue or a C6 to C24 fatty acid residue; b) at least 2 lactic acid residues; and c) at least 2 oxyethylene groups; and wherein the compounds comprise at least two ether bonds and at least two ester bonds. A process for producing the compounds is also described, comprising reacting a) at least one of: a polysorbate, a C6 to C24 fatty alcohol ethoxylate or a C6 to C24 fatty acid ethoxylate; and b) lactide; wherein the compound comprises at least 2 lactic acid residues and at least 2 oxyethylene groups, and the use of such compounds as fibre finishes in non-woven materials such as personal hygiene products and/or as surfactants in cleaning applications such as home care formulations.