Polylactic Acid Color Acceptor for Biodegradable Heat-Sensitive Recording

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Solution Overview

Problem

Heat-sensitive recording materials containing certain color acceptors, such as bisphenol A and bisphenol S, raise environmental concerns, necessitating a biodegradable and environmentally friendly alternative that remains economically viable.

Innovation Solution

A novel color acceptor based on lactic acid monomers, specifically polylactic acid, is used to react with dye precursors to form a visually recognizable color, with oligomers of polylactic acid grouped around divalent or trivalent acids to enhance reactivity, replacing traditional color acceptors like bisphenol A and bisphenol S.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If traditional color acceptors like bisphenol A and bisphenol S are used in heat-sensitive recording materials, then the recording materials function effectively, but environmental harm increases due to non-biodegradability

Engineering Contradiction:
Improveenvironmental harmVSAvoidrecording material functionality
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the chemical composition parameter of the color acceptor from traditional non-biodegradable compounds (bisphenol A, bisphenol S) to polylactic acid, which is biodegradable while maintaining the necessary chemical reactivity with dye precursors for effective recording material functionality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite material structure by combining polylactic acid oligomers with divalent or trivalent acids to create a color acceptor that achieves both biodegradability and enhanced reactivity, resolving the contradiction between environmental friendliness and functional performance

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If polylactic acid is used as color acceptor to improve biodegradability, then environmental soundness improves, but reactivity with dye precursors may be insufficient

Engineering Contradiction:
ImprovebiodegradabilityVSAvoidreactivity with dye precursors
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent segments the polylactic acid into oligomer forms with different chain lengths and groups them around divalent or trivalent acid cores, creating multiple reactive carboxyl groups that enhance dye precursor reaction while maintaining the biodegradable polylactic acid backbone structure

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent creates a composite molecular structure combining polylactic acid oligomers with divalent/trivalent acids, where the composite architecture provides both the biodegradable characteristics of polylactic acid and the enhanced reactivity needed for effective color formation with dye precursors

Inventive Principle:
Principle #40Composite materials

3Reliability

If oligomers of polylactic acid are grouped around n-valent acids to increase carboxyl groups, then reactivity improves, but manufacturing complexity increases

Engineering Contradiction:
Improvequantity of usable carboxyl groupsVSAvoidsynthesis complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent identifies divalent and trivalent acids as universal building blocks that can be combined with polylactic acid oligomers to create color acceptors with varying numbers of carboxyl groups, providing a systematic approach to increasing reactivity while maintaining manageable synthesis complexity through standardized coupling methods

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of polylactic acid as a color acceptor in heat-sensitive recording materials provides a completely biodegradable and environmentally friendly solution that maintains economic practicality, ensuring the recording materials are both effective and sustainable.

Implementation Method 1

a novel color acceptor which is capable of reacting with a dye precursor in a color-forming manner

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

heat-sensitive recording material having such a color acceptor

Methodology Applied
Scientific EffectThermal reaction: Heating

Data Source

PatentUS9308762B2Color acceptor reacting in a color-forming manner to a pigment precursor and heat-sensitive recording material having such a color acceptor
Publication Date: 2016.04.12 MITSUBISHI HITEC PAPER EURO
  • US9308762B2 patent drawing
  • US9308762B2 patent drawing
  • US9308762B2 patent drawing

AI summary

A color acceptor for chemical reaction with a dye precursor to form a visually recognizable color. The color acceptor is constructed of lactic acid monomers. Also disclosed is a heat-sensitive recording material with a substrate and a heat-sensitive recording layer, wherein the heat-sensitive recording layer contains at least one dye precursor and at least one color acceptor which react with one another in a color-forming manner when heat is applied, and wherein the color acceptor is constructed of lactic acid monomers.