Polymer Adhesive Viscosity Reduction via Radical Shear Treatment

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Adhesives based on ethylene-propylene rubber and semi-crystalline olefinic polymers face challenges with high melt viscosity, which limits their application in scenarios requiring low viscosity and high polymer proportion.

Innovation Solution

Treating polymer blends of ethylene-propylene rubber and semi-crystalline olefinic polymers with radical donors under shear stress above the softening point to reduce melt viscosity, resulting in a polymer system with lower viscosity and narrowed molecular weight distribution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If adhesives are made from EPR and semi-crystalline olefinic polymers to achieve high cohesive strength, then adhesive strength is improved, but melt viscosity becomes too high for applications requiring low viscosity

Engineering Contradiction:
Improvecohesive strengthVSAvoidmelt viscosity
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent applies parameter changes by modifying the molecular weight distribution of the polymer blend through controlled degradation processes. By changing the molecular parameters (reducing average molecular weight while maintaining composition), the adhesive achieves both low melt viscosity for ease of application and high cohesive strength for bonding performance.

Inventive Principle:
Principle #35Parameter changes

2Strength

If polymer proportion in adhesive formulation is increased to improve adhesive performance, then adhesive strength is improved, but viscosity increases making it unsuitable for applications requiring low viscosity

Engineering Contradiction:
Improveadhesive strengthVSAvoidviscosity
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent resolves this contradiction by changing the molecular weight distribution parameters of the polymer. Through controlled degradation, the adhesive formulation can incorporate high polymer proportions (improving strength) while maintaining low viscosity (improving applicability) by reducing the average molecular weight of the polymer chains.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process achieves a significant reduction in melt viscosity, enhancing the adhesive's flexibility and adhesion properties while maintaining high cohesive strength, making it suitable for various applications.

Implementation Method 1

treating at least one polymer blend starting material with at least one radical donor under shear stress at a temperature above the softening point of said polymer blend starting material

Methodology Applied
Scientific EffectRadical degradation: Pyrolysis

Implementation Method 2

treating at least one polymer blend starting material with at least one radical donor under shear stress at a temperature above the softening point

Methodology Applied
Scientific EffectShear stress: Shear Stress

Data Source

PatentUS9290680B2Adhesives made from polymer systems
Publication Date: 2016.03.22 HENKEL KGAA

AI summary

The present invention relates to an adhesive, comprising at least one polymer system obtained by a process for reducing the melt viscosity of at least one polymer blend starting material, wherein the process comprises the step of treating at least one polymer blend with at least one radical donor under shear stress at a temperature above the softening point of said polymer blend.