Polymer Blend Inhibitors for Scale Prevention in Desalination
Find Innovative SolutionsGenerate Solutions
Solution Overview
Problem
Current polymer solutions for preventing mineral deposits in water-conducting systems, such as calcium and magnesium salts, are inadequate due to sensitivity to temperature, limited effectiveness against certain salts, and high costs associated with removal methods.
Innovation Solution
A polymer mixture comprising specific weight percentages of water-soluble or water-dispersible polymers with defined molecular weights and monomers, including olefins, carboxylic acids, anhydrides, sulfonic acid groups, and nonionic monomers, which when combined, exhibit enhanced effectiveness in inhibiting calcium carbonate, calcium sulfate, and basic magnesium salt deposits.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Productivity
If high process temperatures are used to increase evaporation efficiency in desalination plants, then energy consumption decreases and productivity improves, but calcium carbonate, calcium sulfate, and magnesium hydroxide precipitate and form deposits
Solution Approach 1:
The patent applies preliminary action by adding polymer inhibitors to the water system before heating and evaporation processes occur. These polymers are预先 introduced to adsorb onto potential deposit-forming surfaces and inhibit crystal growth, preventing mineral deposits from forming even when high temperatures cause supersaturation. This allows the system to operate at optimal temperatures without subsequent cleaning requirements.
Solution Approach 2:
The patent uses polymer inhibitors as intermediary substances that mediate between the water system and mineral salts. These polymers contain functional groups that interact with calcium, magnesium, and sulfate ions, forming soluble complexes that prevent precipitation. The polymers act as a buffer layer between the high-temperature evaporation process and the mineral salts, allowing efficient operation without deposits.
2Reliability
If mechanical and chemical cleaning methods are used to remove deposits, then production downtimes are reduced and system efficiency is maintained, but costs increase and production interruptions occur
Solution Approach 1:
The patent applies preliminary action by continuously maintaining the water system in a deposit-free state through polymer inhibition, eliminating the need for periodic cleaning operations. The polymers are dosed continuously or periodically to maintain protective coverage on surfaces, preventing deposits from forming to problematic levels, thus avoiding production interruptions for maintenance.
Solution Approach 2:
The patent implements self-service by enabling the water system to protect itself against deposits through the continuous action of polymer inhibitors. The polymers adsorb onto surfaces and actively prevent crystal growth and adhesion, allowing the system to maintain itself without external cleaning interventions. This self-protecting mechanism eliminates the need for scheduled maintenance shutdowns.
3Reliability
If low molecular weight polyacrylic acids are used as scale preventers, then effectiveness against calcium carbonate improves, but effectiveness against calcium sulfate and basic magnesium salts is limited
Solution Approach 1:
The patent applies composite materials by combining multiple polymer types with different chemical structures and functional groups into a synergistic mixture. The blend includes polymers with carboxyl groups for calcium carbonate inhibition, sulfonate groups for calcium sulfate prevention, and amino groups for magnesium salt control. This composite polymer system provides broad-spectrum protection against all major deposit types simultaneously, overcoming the limitations of single-polymer approaches.
Solution Approach 2:
The patent achieves universality by designing a polymer mixture where each component targets specific mineral salts while the combination provides comprehensive protection. The polymers contain diverse functional groups (carboxyl, sulfonate, amino, hydroxyl) that can interact with different cations and anions, enabling a single dosing solution to prevent multiple types of deposits across varying water chemistry conditions and temperature ranges.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The polymer mixture significantly improves deposit inhibition, particularly at higher temperatures, reducing production downtimes and energy consumption in desalination plants by effectively preventing calcium carbonate, calcium sulfate, and basic magnesium salt precipitation.
Implementation Method 1
low molecular weight polyacrylic acids and their salts produced by radical polymerization are used as scale preventers in industrial water treatment and in seawater desalination due to their dispersing and crystal growth-inhibiting properties
Implementation Method 2
low molecular weight polyacrylic acids and their salts produced by radical polymerization are used as scale preventers in industrial water treatment and in seawater desalination due to their dispersing and crystal growth-inhibiting properties
Implementation Method 3
low molecular weight polyacrylic acids and their salts produced by radical polymerization are used as scale preventers in industrial water treatment and in seawater desalination due to their dispersing and crystal growth-inhibiting properties
Data Source
AI summary
The invention relates to a polymer blend in solid or aqueous form containing, relative to the polymer content, (A) 5 to 95 wt% of a water-soluble or water-dispersible polymer with an average molecular weight of 1000 to 20000 g/mol consisting of (a1) 20 to 80 wt% of at least one monomer, selected from the group consisting of C2-C8 olefins, allyl alcohol, isoprenol, C1-C4 alkyl vinyl ethers and vinyl esters of C1-C4 monocarboxylic acids, (a2) 20 to 80 wt% of at least one monoethylenically unsaturated C3-C8 carboxylic acid, an anhydride or a salt thereof, (a3) 0 to 50 wt% of one or more monomers containing sulphonic acid groups, (B) 5 to 95 wt% of a water-soluble or water-dispersible polymer with an average molecular weight of 1000 to 50000 g/mol consisting of (b1) 30 to 100 wt% of at least one monoethylenically unsaturated C3-C8 carboxylic acid, an anhydride or a salt thereof, (b2) 0 to 70 wt% of one or more monomers containing sulphonic acid groups, (b3) 0 to 70 wt% of at least one non-ionic monomer of formula (I), H2C=C(R1)(CH2)xO[R2-O]o-R3, wherein R1 represents hydrogen or methyl, R2 represents the same or different, linear or branched C2-C6 alkylene groups, which can be arranged block-wise or statistically, and R3 represents hydrogen or a straight-chain or branched C1-C4 alkyl group, x representing 0, 1 or 2 and o for a number between 3 and 50.

