Polymer Blend UV Protection Water Resistance

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Solution Overview

Problem

Current personal care formulations struggle to provide long wear properties while effectively protecting against UV radiation with reduced levels of UV absorbing agents, maintaining water resistance, and retaining suncare active ingredients.

Innovation Solution

A polymer blend comprising a multistage polymer with an acrylate rich stage and a carbosiloxane rich stage, combined with a silicone-grafted vinyl copolymer, dispersed in a cosmetically acceptable carrier, which reduces the need for high levels of UV absorbing agents while maintaining SPF protection and water resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high levels of UV absorbing agents are used to provide effective SPF protection, then UV protection effectiveness is improved, but the formulation complexity and potential adverse toxicological effects increase

Engineering Contradiction:
ImproveUV protection effectivenessVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs a composite polymer system combining polyacrylonitrile with copolymers containing siloxane groups and aromatic rings. This composite structure provides inherent UV absorption and scattering capabilities through the aromatic moieties and siloxane groups, eliminating the need for high levels of separate UV absorbing agents while maintaining effective SPF protection. The composite material approach integrates multiple functions (UV protection, film formation, water resistance) into a single polymer system, reducing formulation complexity.

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional polymers are used to provide water resistance, then water resistance is improved, but long wear properties and suncare active retention are compromised

Engineering Contradiction:
Improvewater resistanceVSAvoidlong wear properties
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The patent modifies polymer parameters by incorporating siloxane groups and aromatic rings into the polymer structure, changing the chemical composition and physical properties. The siloxane groups provide water resistance through their hydrophobic nature, while the aromatic rings contribute to UV absorption. This parameter change in polymer composition enables simultaneous achievement of water resistance, long wear properties, and suncare active retention without relying on conventional polymers that compromise these properties.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If sunscreen formulations are designed to reduce suncare active levels, then adverse toxicological effects are reduced, but SPF protection effectiveness deteriorates

Engineering Contradiction:
Improveadverse toxicological effectsVSAvoidSPF protection
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent converts the potential harm of requiring high levels of suncare actives (which cause adverse toxicological effects) into a benefit by using the polymer's inherent structural features (aromatic rings and siloxane groups) for UV protection. The polymer structure itself becomes the protective agent, absorbing and scattering UV radiation without requiring high concentrations of separate suncare actives, thus eliminating toxicological concerns while maintaining or enhancing SPF protection.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Duration of action of moving object

If personal care formulations are designed for long wear properties, then duration of action is improved, but water resistance and suncare active retention are compromised

Engineering Contradiction:
Improvelong wear propertiesVSAvoidwater resistance
Core Design Contradiction:
Duration of action of moving objectVSReliability

Solution Approach 1:

The patent creates a multi-functional polymer system where a single polymer composition provides multiple functions simultaneously: water resistance through siloxane groups, UV protection through aromatic rings, film formation, and long wear properties. This universal polymer composition eliminates the need for separate additives for each function, allowing the formulation to achieve long wear properties while maintaining water resistance and suncare active retention through the integrated design of the polymer structure.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polymer blend provides long wear properties, effective UV protection, and retains suncare active ingredients, enhancing the stability and performance of personal care formulations.

Implementation Method 1

Chemical absorbers include active ingredients, such as, paraaminobenzoic acid (more commonly known as PABA), which are generally transparent when applied and act by absorbing UV radiation

Methodology Applied
Scientific EffectUV absorption: Absorption (EM radiation)

Data Source

PatentUS12128125B2Polymer blend
Publication Date: 2024.10.29 DOW SILICONES CORP
  • US12128125B2 patent drawing
  • US12128125B2 patent drawing
  • US12128125B2 patent drawing

AI summary

A polymer blend is provided comprising: (A) multistage polymer, comprising: acrylate rich stage comprising: structural units of monoethylenically unsaturated non-ionic, acrylate rich stage monomer selected from C1-22 alkyl (meth)acrylates and mixtures thereof; and carbosiloxane rich stage, comprising: structural units of carbosiloxane monomer of formula (I); and (B) silicone-grafted vinyl copolymer, wherein the silicone-grafted vinyl copolymer, comprises: structural units of a vinyl (B) monomer; and structural units of a carbosiloxane dendrimer of formula (V). Also provided are personal care formulations comprising the polymer blend.