Polymer Blend UV Protection Water Resistance
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Solution Overview
Problem
Current personal care formulations struggle to provide long wear properties while effectively protecting against UV radiation with reduced levels of UV absorbing agents, maintaining water resistance, and retaining suncare active ingredients.
Innovation Solution
A polymer blend comprising a multistage polymer with an acrylate rich stage and a carbosiloxane rich stage, combined with a silicone-grafted vinyl copolymer, dispersed in a cosmetically acceptable carrier, which reduces the need for high levels of UV absorbing agents while maintaining SPF protection and water resistance.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If high levels of UV absorbing agents are used to provide effective SPF protection, then UV protection effectiveness is improved, but the formulation complexity and potential adverse toxicological effects increase
Solution Approach 1:
The patent employs a composite polymer system combining polyacrylonitrile with copolymers containing siloxane groups and aromatic rings. This composite structure provides inherent UV absorption and scattering capabilities through the aromatic moieties and siloxane groups, eliminating the need for high levels of separate UV absorbing agents while maintaining effective SPF protection. The composite material approach integrates multiple functions (UV protection, film formation, water resistance) into a single polymer system, reducing formulation complexity.
2Reliability
If conventional polymers are used to provide water resistance, then water resistance is improved, but long wear properties and suncare active retention are compromised
Solution Approach 1:
The patent modifies polymer parameters by incorporating siloxane groups and aromatic rings into the polymer structure, changing the chemical composition and physical properties. The siloxane groups provide water resistance through their hydrophobic nature, while the aromatic rings contribute to UV absorption. This parameter change in polymer composition enables simultaneous achievement of water resistance, long wear properties, and suncare active retention without relying on conventional polymers that compromise these properties.
3Object-affected harmful factors
If sunscreen formulations are designed to reduce suncare active levels, then adverse toxicological effects are reduced, but SPF protection effectiveness deteriorates
Solution Approach 1:
The patent converts the potential harm of requiring high levels of suncare actives (which cause adverse toxicological effects) into a benefit by using the polymer's inherent structural features (aromatic rings and siloxane groups) for UV protection. The polymer structure itself becomes the protective agent, absorbing and scattering UV radiation without requiring high concentrations of separate suncare actives, thus eliminating toxicological concerns while maintaining or enhancing SPF protection.
4Duration of action of moving object
If personal care formulations are designed for long wear properties, then duration of action is improved, but water resistance and suncare active retention are compromised
Solution Approach 1:
The patent creates a multi-functional polymer system where a single polymer composition provides multiple functions simultaneously: water resistance through siloxane groups, UV protection through aromatic rings, film formation, and long wear properties. This universal polymer composition eliminates the need for separate additives for each function, allowing the formulation to achieve long wear properties while maintaining water resistance and suncare active retention through the integrated design of the polymer structure.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The polymer blend provides long wear properties, effective UV protection, and retains suncare active ingredients, enhancing the stability and performance of personal care formulations.
Implementation Method 1
Chemical absorbers include active ingredients, such as, paraaminobenzoic acid (more commonly known as PABA), which are generally transparent when applied and act by absorbing UV radiation
Data Source
AI summary
A polymer blend is provided comprising: (A) multistage polymer, comprising: acrylate rich stage comprising: structural units of monoethylenically unsaturated non-ionic, acrylate rich stage monomer selected from C1-22 alkyl (meth)acrylates and mixtures thereof; and carbosiloxane rich stage, comprising: structural units of carbosiloxane monomer of formula (I); and (B) silicone-grafted vinyl copolymer, wherein the silicone-grafted vinyl copolymer, comprises: structural units of a vinyl (B) monomer; and structural units of a carbosiloxane dendrimer of formula (V). Also provided are personal care formulations comprising the polymer blend.


