Polymer-Bonded Perylene Dyes for Ink Solubility

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Solution Overview

Problem

Perylene dyes have low solubility and dispersibility in liquid media, limiting their suitability for applications in printing inks and other compositions, making it difficult to distinguish authentic from counterfeit products and secure documents.

Innovation Solution

Binding perylene dyes to a polymer that is soluble in the liquid medium, such as a phenolic resin, to increase their solubility and dispersibility, using covalent bonding and specific polar groups to enhance their properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If perylene dyes are used as colorants in printing ink compositions, then their fluorescence and color properties are improved, but their solubility and dispersibility in liquid media deteriorate

Engineering Contradiction:
ImprovefluorescenceVSAvoidsolubility
Core Design Contradiction:
Illumination intensityVSQuantity of substance

Solution Approach 1:

The patent applies composite materials by combining perylene dye molecules with polymer chains to form polymer-bonded perylene dyes. This composite structure integrates the fluorescent properties of perylene dyes with the solubility characteristics of polymers, resolving the contradiction between maintaining fluorescence and improving solubility in liquid media

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent uses polymer chains as intermediary carriers to bond with perylene dyes. The polymer acts as a mediator that facilitates the dissolution and dispersibility of perylene dyes in liquid media while preserving their fluorescent properties, thus resolving the solubility issue without compromising the illumination intensity

Inventive Principle:
Principle #24Intermediary (Mediator)

2Illumination intensity

If perylene dyes are used as colorants in printing ink compositions, then their color properties are improved, but their dispersibility in liquid media deteriorates

Engineering Contradiction:
Improvecolor propertiesVSAvoiddispersibility
Core Design Contradiction:
Illumination intensityVSQuantity of substance

Solution Approach 1:

The patent creates composite materials by bonding perylene dyes to polymer chains, forming polymer-bonded perylene dyes that maintain the excellent color properties of perylene while gaining improved dispersibility in liquid media through the polymer component

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the physical and chemical parameters of perylene dyes by bonding them to polymer chains with specific molecular weights and functional groups. This parameter change transforms the original poor dispersibility into improved dispersibility while maintaining the desired color properties

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polymer-bonded perylene dyes exhibit improved solubility and dispersibility, enabling their effective use in printing inks and other compositions, enhancing the ability to authenticate and secure documents by providing clear differentiation from counterfeit items.

Implementation Method 1

the perylene dye may be covalently bonded to the polymer

Methodology Applied
Scientific EffectCovalent bonding: Chemical Bonding

Implementation Method 2

the liquid medium may be a polar liquid medium... the polymer may comprise at least one (recurring) monomer unit that comprises at least one polar group

Methodology Applied
Scientific EffectPolar interaction: Solvation

Data Source

PatentUS9029442B2Polymer-bonded perylene dyes and compositions containing same
Publication Date: 2015.05.12 SICPA HOLDING SA
  • US9029442B2 patent drawing
  • US9029442B2 patent drawing
  • US9029442B2 patent drawing

AI summary

A method of increasing the solubility and/or dispersibility of a perylene dye in a liquid medium. The method comprises binding the perylene dye to a polymer which is soluble in the liquid medium. This abstract is neither intended to define the invention disclosed in this specification nor intended to limit the scope of the invention in any way.