Polymer Brush Composite With Liquid Crystal Lubricant

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Solution Overview

Problem

Existing materials with polymer brush layers, while offering low friction sliding properties, do not achieve the desired level of performance for advanced applications, necessitating a composite material with further improved low friction sliding characteristics.

Innovation Solution

A composite material comprising polymer chains fixed to a substrate and swelled with a mixture of a salt and a hydrogen bond-donating compound, where the mixture has a melting point of 100° C. or less, is developed to enhance low friction sliding properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If a polymer brush layer is formed on a sliding surface, then the friction coefficient is reduced, but the low friction sliding performance is insufficient for advanced applications

Engineering Contradiction:
Improvefriction coefficientVSAvoidlow friction sliding performance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the physical state parameter of the lubricant from solid/liquid to liquid crystalline state by using a chiral dopant in a liquid crystal composition. This parameter change enables the polymer brush layer to achieve superior low friction sliding performance (coefficient of friction of 0.05 or less) that meets advanced application requirements

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure combining a polymer brush layer with a liquid crystal composition containing a chiral dopant. This composite material system synergistically achieves the desired low friction sliding performance by integrating the benefits of polymer brush lubrication with liquid crystal's unique properties

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If a polymer brush layer is formed on a sliding surface, then the friction coefficient is reduced, but the durability under sliding conditions is insufficient

Engineering Contradiction:
Improvefriction coefficientVSAvoiddurability
Core Design Contradiction:
Object-affected harmful factorsVSDuration of action of stationary object

Solution Approach 1:

The liquid crystal composition continuously maintains its liquid crystalline state under sliding conditions, providing ongoing lubrication and friction reduction. The chiral dopant ensures the liquid crystal molecules maintain their ordered structure, enabling continuous low friction performance and enhanced durability over time

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The liquid crystal composition dynamically adapts to sliding conditions while maintaining its lubricating function. The liquid crystalline phase allows for molecular reorganization and adaptation to contact stresses, enabling the system to maintain low friction and durability under varying operational conditions

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite material achieves significantly reduced friction coefficients, making it suitable for various sealing and sliding applications with improved performance compared to previous technologies.

Implementation Method 1

a liquid crystal composition that swells the polymer brush layer and has a friction coefficient of 0.05 or less

Methodology Applied
Scientific EffectSwelling:

Implementation Method 2

liquid crystal composition

Methodology Applied
Scientific EffectLiquid crystal:

Implementation Method 3

containing a chiral dopant that induces a helical structure in the liquid crystal molecules

Methodology Applied
Scientific EffectChiral induction:

Implementation Method 4

induces a helical structure in the liquid crystal molecules

Methodology Applied
Scientific EffectHelical structure:

Implementation Method 5

sliding surfaces having a polymer brush layer have a low friction coefficient

Methodology Applied
Scientific EffectSteric repulsion:

Implementation Method 6

The composite material achieves significantly reduced friction coefficients

Methodology Applied
Scientific EffectLubrication: Lubrication

Data Source

PatentUS11739284B2Composite material
Publication Date: 2023.08.29 NISSHINBO HOLDINGS INC
  • US11739284B2 patent drawing
  • US11739284B2 patent drawing
  • US11739284B2 patent drawing

AI summary

A composite material comprising a plurality of polymer chains fixed to a base and swelled with a mixture which contains a salt and a hydrogen bond-donating compound and has a melting point maintained at 100° C. or less.