Polymer Compound with Crosslinkable Groups for Light-Emitting Devices

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Solution Overview

Problem

Light emitting devices produced using existing polymer compounds do not have sufficient external quantum yield.

Innovation Solution

A polymer compound with specific constitutional units and crosslinkable groups is developed, enhancing the external quantum yield of light emitting devices. The polymer compound includes constitutional units represented by specific formulas and crosslinkable groups, improving the device's performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If existing polymer compounds are used in light emitting devices, then the device can be produced with conventional materials, but the external quantum yield is insufficient

Engineering Contradiction:
Improveexternal quantum yieldVSAvoidmaterial selection flexibility
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent modifies the chemical structure of polymer compounds by introducing specific constitutional units with crosslinkable groups, changing the material parameters to achieve higher external quantum yield while maintaining manufacturability through conventional processing methods

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite polymer compound combining light-emitting constitutional units with crosslinkable constitutional units, where the synergistic interaction between these components achieves high external quantum yield while preserving ease of manufacture through solution processing

Inventive Principle:
Principle #40Composite materials

2Reliability

If polymer compounds with crosslinkable groups are introduced to improve external quantum yield, then the device performance is enhanced, but the molecular structure complexity increases

Engineering Contradiction:
Improveexternal quantum yieldVSAvoidmolecular structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent divides the polymer compound into distinct functional segments: light-emitting constitutional units and crosslinkable constitutional units, where each segment performs its specific function independently, simplifying the design complexity while achieving high external quantum yield

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The crosslinkable constitutional units serve multiple functions: they enable crosslinking for device stability and simultaneously contribute to the overall light-emitting performance, reducing the need for separate functional components and simplifying the molecular structure

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polymer compound significantly enhances the external quantum yield and luminance life of light emitting devices, making them more efficient and effective.

Implementation Method 1

a crosslinkable constitutional unit having at least one crosslinkable group selected from (XL-1) to (XL-9) or (XL-11) to (XL-17) of Group A of crosslinkable groups

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Data Source

PatentEP3187522B1Polymer compound and light-emitting element using same
Publication Date: 2019.12.04 SUMITOMO CHEM CO LTD
  • EP3187522B1 patent drawing
  • EP3187522B1 patent drawing
  • EP3187522B1 patent drawing

AI summary

Provided is a polymer compound which is useful for production of a light emitting device excellent in external quantum yield. A polymer compound comprising a constitutional unit represented by the formula (1), wherein a1 and a2 represent 0 or 1, ArA1 and ArA3 represent an arylene group or the like,and in each of ArA1 and ArA3 at least one atom adjacent to an atom forming a bond to the constitutional unit adjacent to the each of ArA1 and ArA3 has an alkyl group or the like as a substituent, ArA2 represents a phenylene group, ArA4 represents an arylene group or the like, RA1, RA2 and RA3 represent an aryl group or the like, and when a2 is 0, RA1 represents an aryl group in which two or more rings are condensed (the number of carbon atoms constituting the rings of the aryl group is 10 or more) or the like.