Polymer Dispersant Composition for Stable TiO2 White Paint

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Solution Overview

Problem

White paint faces issues with TiO2 aggregation and precipitation, leading to instability and incompatibility with resin, which degrades its properties.

Innovation Solution

A polymer formed by capping a copolymer-graft-polylactone with an alcohol, copolymerized from an anhydride monomer with a double bond and a monomer with a double bond, is used as a dispersant to stabilize TiO2 in a dispersion and paint.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If TiO2 is used in white paint to achieve high opacity and tinting ability, then the paint's covering power is improved, but TiO2 easily aggregates and precipitates, causing instability and incompatibility with resin

Engineering Contradiction:
ImproveopacityVSAvoiddispersion stability
Core Design Contradiction:
Illumination intensityVSStability of the object's composition

Solution Approach 1:

The patent introduces a specifically designed polymer dispersant as an intermediary substance between TiO2 pigment and resin binder. This dispersant contains hydrophobic segments that adsorb onto TiO2 particle surfaces and hydrophilic segments that interact with the resin matrix, creating a bridge that prevents aggregation while maintaining compatibility. The dispersant acts as a mediator that resolves the incompatibility between inorganic TiO2 and organic resin, enabling stable dispersion without sacrificing opacity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the chemical and physical parameters of the dispersant system by using a copolymer with specific composition ratios (anhydride monomer 20-40%, vinyl monomer 60-80%), controlled molecular weight (5,000-50,000), and specific functional group content (carboxyl 0.1-5.0 mmol/g). These parameter optimizations ensure the dispersant has the right balance of adsorption capability and steric stabilization, preventing TiO2 aggregation while maintaining paint stability and resin compatibility.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If TiO2 is used in white paint to achieve high tinting ability, then the paint's color strength is improved, but TiO2 aggregates and precipitates, degrading paint properties

Engineering Contradiction:
Improvetinting abilityVSAvoidpaint property stability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The polymer dispersant serves as a mediator that maintains the uniform distribution of TiO2 particles throughout the paint matrix. By adsorbing onto TiO2 surfaces and extending into the continuous phase, the dispersant prevents particle aggregation and sedimentation, thereby maintaining consistent tinting ability and color strength over time while improving overall paint reliability and storage stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite dispersant system combining multiple functional segments: anhydride-derived polar groups for strong TiO2 surface interaction, vinyl-derived hydrocarbon chains for steric stabilization, and grafted polylactone segments for enhanced compatibility. This composite molecular structure provides multifunctional protection against aggregation and precipitation, ensuring both high tinting ability and long-term paint property stability.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polymer effectively disperses TiO2, maintaining stability and compatibility with resin, resulting in a paint with improved gloss and opacity.

Implementation Method 1

The polymer effectively disperses TiO2, maintaining stability and compatibility with resin

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

The polymer is formed by capping a copolymer-graft-polylactone with an alcohol, wherein the copolymer is copolymerized from an anhydride monomer with a double bond, a monomer with a double bond, and an initiator

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS12522724B2Polymer, dispersion, and paint
Publication Date: 2026.01.13 IND TECH RES INST
  • US12522724B2 patent drawing
  • US12522724B2 patent drawing
  • US12522724B2 patent drawing

AI summary

A polymer is formed by capping a copolymer-graft-polylactone with an alcohol, wherein the copolymer is copolymerized from an anhydride monomer with a double bond, a monomer with a double bond, and an initiator. The polymer can be mixed with an organic solvent and pigment powder to form a dispersion. The dispersion can be mixed with a binder to form a paint.