Water-Soluble Polymer Dosing for Paper Wet Strength

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Solution Overview

Problem

The initial wet structure strength of paper limits the maximum force that can be applied to the paper sheet during the transition from the press section to the dryer section in paper machines, restricting machine speed and efficiency.

Innovation Solution

Incorporating a water-soluble polymer obtained by Hofmann degradation of acrylamide and/or methacrylamide into the paper stock, with specific dosing and processing conditions to enhance the initial wet structure strength, allowing for higher solids content and improved paper machine operation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the initial wet structure strength is increased to allow higher pull-off forces and faster machine operation, then productivity increases, but the process complexity increases due to specific polymer dosing and processing requirements

Engineering Contradiction:
Improvemachine speedVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The water-soluble polymer is dosed into the paper stock before sheet formation in the wire section, allowing the polymer to be incorporated into the fiber network in advance. This preliminary action ensures the polymer is present when the sheet is formed and pressed, providing enhanced wet structure strength without requiring complex post-processing equipment

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention specifies dosing the water-soluble polymer at concentrations of 0.1 to 5 kg per ton of dry fiber, with fiber concentrations in the range of 20 to 40 g/l. These parameter changes optimize the polymer's effectiveness in enhancing wet structure strength while maintaining processability through standard paper machine equipment

Inventive Principle:
Principle #35Parameter changes

2Strength

If the solids content of the paper web after pressing is increased to improve wet structure strength, then the initial wet structure strength improves, but the energy consumption increases due to higher pressing requirements

Engineering Contradiction:
Improveinitial wet structure strengthVSAvoidenergy consumption
Core Design Contradiction:
StrengthVSUse of energy by stationary object

Solution Approach 1:

The water-soluble polymer acts as an intermediary substance that enhances the bonding between fibers in the paper web. By dosing the polymer into the stock before sheet formation, it facilitates fiber-to-fiber bonding during pressing, allowing adequate wet structure strength to be achieved at lower solids content and reduced pressing energy requirements

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If the pull-off force applied to the paper sheet is increased to improve production efficiency, then productivity increases, but the risk of sheet tearing increases if the initial wet structure strength is insufficient

Engineering Contradiction:
Improveproduction efficiencyVSAvoidsheet integrity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The water-soluble polymer is incorporated into the paper stock before sheet formation and pressing, preliminarily strengthening the fiber network. This allows the sheet to withstand higher pull-off forces during transfer from the press section to the dryer section without tearing, enabling increased production efficiency while maintaining sheet integrity

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The polymer reinforcement acts as a cushioning mechanism that pre-strengthens the paper web against the high mechanical stresses of high-speed operation. This beforehand cushioning allows the use of higher pull-off forces without risking sheet failure

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The enhanced initial wet structure strength enables higher pull-off forces and faster paper machine operation without tearing, improving production efficiency and paper quality.

Implementation Method 1

The at least one water-soluble polymer is obtainable by Hofmann degradation of a polymer containing acrylamide and/or methacrylamide

Methodology Applied
Scientific EffectHofmann degradation:

Implementation Method 2

dewatering a filler-containing paper stock which contains at least one water-soluble polymer, with sheet formation in the wire section

Methodology Applied
Scientific EffectDewatering:

Implementation Method 3

pressing the paper in the press section, resulting in a paper stock with a fiber concentration of 5 to 15 g/l and a solids content of G(x) wt.% or greater

Methodology Applied
Scientific EffectCompression: Compression

Data Source

PatentEP2888404B1Method for producing paper, paperboard and cardboard
Publication Date: 2018.07.18 BASF SE
  • EP2888404B1 patent drawing
  • EP2888404B1 patent drawing
  • EP2888404B1 patent drawing

AI summary

The invention relates to a method for producing paper, paperboard and cardboard, comprising the dehydration of a paper material comprising filler material, which contains at least one water-soluble polymer, forming sheets in the wire section and subsequent pressing of the paper in the press section, wherein the at least one water-soluble polymer is dosed to a paper material having a fiber concentration in the range of 20 to 40 g/l, the paper material is then thinned to a fiber concentration in the range of 5 to 15 g/l, the thinned paper material is dehydrated, forming a sheet, and the sheet is pressed in the press section to a solids content G(x) wt % or greater and G(x) is calculated according to G(x) = 48 + (x -15)∙0.4, where x stands for the numerical value of the filler material content of the dry paper, paperboard or cardboard (in wt %) and G(x) stands for the numerical value of the minimum solids content (in wt %) on which the sheet is pressed, wherein the water-soluble polymer is obtainable via Hofmann reduction of a polymer comprising acrylamide and/or methacrylamide and optionally subsequent post-curing.