High-Density Polymer Drilling Fluid for 240°C and Saturated Salinity

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Solution Overview

Problem

Existing water-based drilling fluids are unable to simultaneously meet the requirements of ultra-high temperature resistance, ultra-high pressure resistance, saturated salt resistance, and environmental protection, making them inadequate for drilling in deep and ultra-deep oil and gas formations.

Innovation Solution

A high-density, environmentally friendly polymer water-based drilling fluid is developed, comprising a micro-crosslinked heterocyclic polymer filtrate reducer, a hyper-branched strongly adsorbed polymer filtrate reducer, a nanometer intercalated complex shearing potentiator, and a flexible outer and rigid inner microsphere plugging agent, which maintains desirable properties for over 10 days under conditions of 240°C, saturated salinity, and high mineralization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional water-based drilling fluids are used, then environmental protection is improved, but temperature resistance deteriorates (cannot resist 240°C)

Engineering Contradiction:
Improveenvironmental protectionVSAvoidtemperature resistance
Core Design Contradiction:
Object-affected harmful factorsVSTemperature

Solution Approach 1:

The patent uses composite polymers including crosslinked polyacrylamide and partially hydrolyzed polyacrylonitrile in specific ratios (0.5-5% and 1-10% respectively) to create a water-based drilling fluid that maintains environmental friendliness while achieving 240°C temperature resistance. The composite structure allows the fluid to withstand ultra-high temperature without compromising biodegradability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies key parameters including pH (maintained at 8-10 through sodium hydroxide addition), polymer concentration ratios, and crosslinking degree to enable the water-based fluid to resist 240°C. The controlled partial hydrolysis of polyacrylonitrile (30-70% degree) creates optimal thermal stability while preserving environmental compatibility.

Inventive Principle:
Principle #35Parameter changes

2Weight of stationary object

If high density (2.4 g/cm³) is achieved, then drilling depth capability is improved, but fluid stability deteriorates under ultra-high temperature and salinity

Engineering Contradiction:
ImprovedensityVSAvoidfluid stability
Core Design Contradiction:
Weight of stationary objectVSStability of the object's composition

Solution Approach 1:

The patent applies different functional polymers to different aspects of fluid performance: crosslinked polyacrylamide (0.5-5%) provides density maintenance and suspension capability for high-density requirements, while partially hydrolyzed polyacrylonitrile (1-10%) provides thermal and salinity stability. This localized functional assignment allows the fluid to maintain 2.4 g/cm³ density with stable composition under 240°C and saturated salt conditions.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent ensures continuous protective action through polymers with prolonged action time (≥72 hours at 240°C). The crosslinked structure and partial hydrolysis create a stable polymer network that continuously maintains fluid properties including density and stability throughout the drilling operation, preventing degradation under ultra-high temperature and salinity.

Inventive Principle:
Principle #20Continuity of useful action

3Temperature

If sulfonated materials are added to improve temperature resistance, then temperature resistance is improved, but environmental protection performance deteriorates

Engineering Contradiction:
Improvetemperature resistanceVSAvoidenvironmental protection performance
Core Design Contradiction:
TemperatureVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and eliminates sulfonated materials from the drilling fluid system while achieving 240°C temperature resistance through alternative polymer chemistry. The solution uses crosslinked polyacrylamide and partially hydrolyzed polyacrylonitrile with carboxyl and amide groups instead of sulfonated polymers, maintaining thermal stability without compromising environmental protection performance.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces expensive and environmentally harmful sulfonated materials with cost-effective, biodegradable polymer combinations. The crosslinked polyacrylamide and partially hydrolyzed polyacrylonitrile system provides equivalent or superior temperature resistance at lower cost with full environmental compatibility, enabling safe disposal after use.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Stability of the object's composition

If high mineralization resistance is achieved, then salt resistance is improved, but rheology control deteriorates

Engineering Contradiction:
Improvesalt resistanceVSAvoidrheology
Core Design Contradiction:
Stability of the object's compositionVSStress or pressure

Solution Approach 1:

The patent creates a dynamic rheological system where the polymer network adapts to salt concentration changes. The crosslinked polyacrylamide and partially hydrolyzed polyacrylonitrile form a flexible gel structure that maintains optimal viscosity and flow properties across varying salt conditions (including saturated NaCl). The pH control (8-10) dynamically adjusts polymer charge states to optimize both salt resistance and rheology simultaneously.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The drilling fluid effectively reduces filtrate loss, maintains good rheology, and suspends weighting materials and drill cuttings for an extended period, preventing well accidents such as collapse, leakage, and blowout, while also being environmentally friendly and easy to maintain.

Implementation Method 1

a micro-crosslinked heterocyclic polymer filtrate reducer

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

micro-crosslinked heterocyclic polymer

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 3

hyper-branched strongly adsorbed polymer filtrate reducer

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 4

nanometer intercalated complex shearing potentiator

Methodology Applied
Scientific EffectIntercalation:

Implementation Method 5

shearing potentiator

Methodology Applied
Scientific EffectShear thickening: Shear Thickening

Implementation Method 6

suspends weighting materials and drill cuttings

Methodology Applied
Scientific EffectBuoyancy: Archimedes' Principle (Buoyancy)

Implementation Method 7

flexible outer and rigid inner microsphere plugging agent

Methodology Applied
Scientific EffectMicrosphere structure: Microsphere

Data Source

PatentUS12269985B1High density environmentally friendly polymer water-based drilling fluid with resistance to 240° C. and saturated salts, preparation method therefor and use thereof
Publication Date: 2025.04.08 CHINA UNIV OF PETROLEUM (EAST CHINA)
  • US12269985B1 patent drawing

AI summary

The present disclosure relates to the technical field of drilling fluid, and discloses a high density environmentally friendly polymer water-based drilling fluid with resistance to 240° C. and saturated salts, a preparation method therefor and use thereof. The water-based drilling fluid comprises a micro-crosslinked heterocyclic polymer filtrate reducer, a hyper-branched strongly adsorbed filtrate reducer, a nanometer intercalated complex shearing potentiator, a flexible outer and rigid inner microsphere plugging agent, and water, wherein the micro-crosslinked heterocyclic polymer filtrate reducer is prepared by reacting sodium p-styrene sulfonate, N,N,N-trimethyl-3-(2-methylallylamino)-1-propyl ammonium chloride, N,N-diethyl acrylamide, N-vinyl caprolactam, tetramethyl ethylenediamine with phenyl triethoxy silane. The high density environmentally friendly polymer water-based drilling fluid with resistance to 240° C. and saturated salts of the present disclosure can exhibit good performance at high temperature and high salinity conditions, and has desirable weighting capability, it can meet the requirements of drilling well in the deep oil and gas formations.