Water-Based Polymer Emulsion for Blister Package Heat Seal

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Solution Overview

Problem

Existing heat seal coatings for blister packages lack stability and safety, as oil-based resins pose fire risks and organic solvents can contaminate packaged goods, while water-soluble alternatives exhibit reduced heat sealability and cause plastic deformation.

Innovation Solution

A polymer emulsion with latex particles formed using a water-soluble polymer emulsifier of specific molecular weight, glass transition temperature, and acid value, which enables excellent heat sealability and coatability without organic solvents, minimizing environmental and health hazards.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If oil-based resin solution is used for heat seal coating, then heat sealability is achieved, but fire risk and organic solvent contamination occur

Engineering Contradiction:
Improveheat sealabilityVSAvoidfire risk and organic solvent contamination
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The invention changes the chemical composition parameters of the heat seal coating by replacing oil-based resins with water-soluble polymer emulsions. Specifically, it uses polymer emulsions containing carboxylic acid groups with controlled molecular weight (10,000-50,000 g/mol) and glass transition temperature (80-120°C), transforming the coating system from organic-solvent-based to water-based while maintaining heat seal performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs water-soluble polymer emulsions that can be easily applied and dried, leaving minimal residual solvent. The water-based system evaporates cleanly compared to oil-based resins, reducing long-term contamination risks while maintaining effective heat seal functionality during the sealing process

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Object-affected harmful factors

If water soluble styrene/acryl-based resin is applied for heat seal coating, then organic solvent contamination is reduced, but heat sealability and manufacturing precision deteriorate

Engineering Contradiction:
Improveorganic solvent contaminationVSAvoidheat sealability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The invention optimizes critical parameters of water-soluble polymer emulsions: molecular weight (10,000-50,000 g/mol), glass transition temperature (80-120°C), and functional group content (carboxylic acid groups). These parameter optimizations enable the water-based emulsion to achieve melt viscosity and adhesion properties necessary for reliable heat sealing, matching or exceeding oil-based resin performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite heat seal coating system by combining water-soluble polymer emulsion with specific additives and controlling the emulsion composition to include styrene-acryl copolymers with enhanced properties. This composite approach maintains the water-based safety advantage while achieving the thermal and adhesive performance of traditional oil-based systems

Inventive Principle:
Principle #40Composite materials

3Object-affected harmful factors

If water soluble styrene/acryl-based resin is applied for heat seal coating, then organic solvent contamination is reduced, but plastic container deformation occurs

Engineering Contradiction:
Improveorganic solvent contaminationVSAvoidplastic container deformation
Core Design Contradiction:
Object-affected harmful factorsVSManufacturing precision

Solution Approach 1:

The invention adjusts the glass transition temperature of the polymer emulsion to 80-120°C and controls molecular weight to ensure the coating remains stable at room temperature and during typical processing. This parameter control prevents premature softening and deformation of the plastic container while enabling effective heat sealing at elevated temperatures

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a coating system with dynamic thermal response: the water-soluble polymer emulsion maintains rigidity at lower temperatures (preventing container deformation) but transitions to a soft, adhesive state at heat sealing temperatures. This dynamic property allows the coating to protect the container during handling while enabling reliable sealing when heated

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polymer emulsion provides stable and safe heat sealability for blister packages, ensuring effective adhesion at high temperatures without room temperature adhesion, and reducing residual solvent risks, thus enhancing safety and performance.

Implementation Method 1

a water soluble polymer emulsifier having a weight average molecular weight of 6000 to 23000 g/mol, a glass transition temperature of 100 to 150°C., and an acid value of 100 to 230 mg KOH/g covers a polymer

Methodology Applied
Scientific EffectSteric stabilization:

Implementation Method 2

the plastic container and the substrate are adhered mainly by heat sealing... stable heat sealability (that is, the property of exhibiting adhesion at high temperature and/or high pressure conditions without exhibiting adhesion at room temperature)

Methodology Applied
Scientific EffectHeat sealing adhesion: Adhesive

Implementation Method 3

have problems of deformation of the plastic container of the blister package when heated to a temperature at which heat sealing is enabled

Methodology Applied
Scientific EffectPlastic deformation: Plasticity

Data Source

PatentUS10053571B2Polymer emulsion having heat sealability for blister package and preparation method thereof
Publication Date: 2018.08.21 HANWHA CHEMICAL CORPORATION
  • US10053571B2 patent drawing
  • US10053571B2 patent drawing
  • US10053571B2 patent drawing

AI summary

The present invention provides a polymer emulsion having heat sealability for a blister package, and a method for preparing the same. Since the polymer emulsion of the present invention includes latex particles having an average particle diameter of a nanosize and a low unimodal particle size distribution, it may exhibit uniform and stable emulsion properties, particularly excellent heat sealability, and thus may be suitably used for a blister package and on the like. Furthermore, the polymer emulsion of the present invention is polymerized in an aqueous medium without using an organic solvent, and thus enables provision of a blister package with minimized harmfulness to a human body and the environment.