Polymer Systems for Subterranean Energy Storage Fluid Leak-Off

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Solution Overview

Problem

Pumped geo-mechanical energy storage systems face significant fluid leak-off issues due to fluid migration through the matrix of the strata, reducing the volume available for electricity generation.

Innovation Solution

Introduce a resin pill containing a cycloalkene and a transition metal compound catalyst capable of ring-opening metathesis polymerization (ROMP) to form a cured resin, which reduces leak-off by transforming into a hardened mass within the fractures, enhancing fluid retention.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If water is pumped into a fracture in a geological formation for energy storage, then the fracture can store pressurized water for later energy generation, but fluid leak-off to other regions of the geological formation reduces the volume of water available for cyclic energy storage

Engineering Contradiction:
Improvevolume of water stored in fractureVSAvoidfluid leak-off to other regions
Core Design Contradiction:
Quantity of substanceVSLoss of substance

Solution Approach 1:

The patent applies local quality by introducing a resin pill that selectively treats specific regions of the fracture, particularly the fracture tip where leak-off is most pronounced. The resin transforms the local permeability characteristics at the fracture tip without affecting the entire fracture system, creating a localized barrier that prevents fluid migration to adjacent regions while maintaining storage capacity in the main fracture zone.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The resin pill is injected into the fracture before the main water storage operation begins. This preliminary action allows the resin to establish its barrier function in advance, preventing fluid leak-off during subsequent pumping and storage cycles. The resin has sufficient time to polymerize and form the hardened mass that blocks leak-off pathways before large volumes of water are introduced into the fracture.

Inventive Principle:
Principle #10Preliminary action

2Productivity

If the fracture is made more permeable to allow water flow in and out, then energy can be generated when water flows through a turbine, but increased permeability allows more fluid to migrate to other regions reducing storage efficiency

Engineering Contradiction:
Improveenergy generation capabilityVSAvoidfluid migration to other regions
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The resin pill creates a localized impermeable barrier specifically at the fracture tip region where fluid would otherwise migrate to unwanted areas. This selective treatment maintains the necessary permeability in the main fracture body for energy generation while creating a local seal that prevents fluid loss to adjacent regions, thus resolving the contradiction between productivity and fluid retention.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The resin acts as an intermediary substance that modifies the fracture's permeability characteristics. It provides a controlled barrier function that allows the fracture to maintain its energy generation capability while preventing unwanted fluid migration. The resin mediates between the need for fluid flow (for energy generation) and the need for fluid retention (for storage efficiency).

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The cured resin effectively minimizes fluid leak-off, increasing the volume of fluid available for electricity generation and improving the efficiency of energy storage systems.

Implementation Method 1

a resin capable of undergoing a ring-opening metathesis polymerization (ROMP) reaction

Methodology Applied
Scientific EffectRing-opening metathesis polymerization (ROMP): Chemical Bonding

Implementation Method 2

a transition metal compound catalyst capable of ring-opening metathesis polymerization (ROMP)

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS20250313746A1Polymer systems for subterranean energy storage
Publication Date: 2025.10.09 HALLIBURTON ENERGY SERVICES INC
  • US20250313746A1 patent drawing
  • US20250313746A1 patent drawing
  • US20250313746A1 patent drawing

AI summary

A method may include: introducing a resin modified cement slurry into a wellbore penetrating a subterranean formation, the subterranean formation comprising a caprock and a carbon dioxide injection zone, the resin modified cement slurry comprising: a resin; a hardener; a hydraulic cement; and water; and setting the resin modified cement slurry to form a set cement wherein the set cement forms a carbonation-resistant barrier in the carbon dioxide injection zone in the subterranean formation.