High Charge Density Polymers for Fertilizer Nutrient Stabilization

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Solution Overview

Problem

Fertilizers often fail to fully utilize nutrients due to reactions that lead to precipitation or clumping of inorganic phosphate, carbonate, or sulfate salts, resulting in low availability for plants, with less than 50% of fertilizers being absorbed by plants and significant losses of phosphorus and nitrogen before application.

Innovation Solution

The development of high charge density polymers that inhibit the precipitation of inorganic phosphate, carbonate, or sulfate salts and disperse inorganic particulates, enhancing the availability of nutrients by stabilizing fertilizer components and improving their uptake by plants.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional fertilizers are applied to soil, then nutrients are provided to plants, but reactions between elements cause precipitation of phosphate minerals that decreases available nutrients

Engineering Contradiction:
Improveavailable phosphorusVSAvoidphosphate precipitation
Core Design Contradiction:
Quantity of substanceVSLoss of substance

Solution Approach 1:

The patent introduces organic acids and chelating agents as intermediary substances that bind to metal ions (Ca2+, Mg2+, Fe3+, Al3+) to form soluble complexes. This prevents these metal ions from reacting with phosphate to form precipitates, thereby maintaining phosphorus availability. The intermediary substances act as buffers that mediate between the phosphate fertilizer and metal ions in the soil.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical parameters of the fertilizer system by incorporating organic acids and chelating agents that alter the solubility and reactivity of phosphate compounds. These parameter changes prevent the formation of insoluble phosphate minerals and maintain nutrients in a plant-available form throughout the soil environment.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If fertilizers are applied to promote plant growth, then nutrient supply increases, but less than 50% of fertilizer is absorbed by plants due to precipitation reactions

Engineering Contradiction:
Improvecrop yieldVSAvoidfertilizer absorption efficiency
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The organic acids and chelating agents serve as mediators that facilitate nutrient availability. By binding to metal ions and preventing phosphate precipitation, they ensure that a higher proportion of applied fertilizer remains in a form that plants can absorb and utilize, thereby improving overall fertilizer use efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates composite fertilizer formulations that combine conventional inorganic fertilizers with organic acids and chelating agents. This composite approach leverages the nutrient-providing capacity of inorganic fertilizers while the organic components prevent precipitation and enhance availability, resulting in more efficient plant uptake.

Inventive Principle:
Principle #40Composite materials

3Quantity of substance

If inorganic phosphate is applied to soil, then phosphorus nutrition is provided, but precipitation with metal ions forms phosphate minerals that reduce nutrient availability

Engineering Contradiction:
Improvephosphorus availabilityVSAvoidphosphate solubility
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The organic acids and chelating agents act as intermediaries that bind to metal ions (Ca2+, Mg2+, Fe3+, Al3+) to form stable soluble complexes. This prevents these metal ions from reacting with phosphate to form insoluble precipitates, thereby maintaining phosphorus in a soluble, plant-available form and stabilizing its composition in the soil.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution increases the efficacy of fertilizer nutrients, leading to higher crop yields and reduced application rates, while also addressing micronutrient interactions like zinc availability, thereby enhancing profitability and optimizing plant growth.

Implementation Method 1

A fertilizer having the ability to prevent or inhibit the precipitation of inorganic phosphate, carbonate, or sulfate salts

Methodology Applied
Scientific EffectPrecipitation inhibition: Precipitation

Implementation Method 2

the ability to disperse inorganic particulates

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentUS12098316B2Compositions for enhancing soil nutrients
Publication Date: 2024.09.24 EVANS BRYAN D
  • US12098316B2 patent drawing
  • US12098316B2 patent drawing
  • US12098316B2 patent drawing

AI summary

Interpolymers useful for enhancing the efficacy of nutrients in soil and fertilizers; and methods of inhibiting the precipitation of, and/or dispersing, inorganic elements.