Conductive Polymer Fuel Marker Detection Device

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Solution Overview

Problem

Conductive polymers used for detecting markers in liquids face stability issues and require bulky equipment, making it difficult to detect markers at low concentrations efficiently and authentically, especially in fuels like diesel and gasoline.

Innovation Solution

A device with a polymer formulation comprising an insulating polymer and a polymer with variable conductivity that changes resistivity upon contact with markers, allowing for reliable detection of low concentrations of markers in fuels using a portable, simple resistivity tester, which includes a heater element and optional distillation for concentration and separation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional conductive polymers are used to detect markers in liquids, then detection capability is provided, but stability deteriorates due to shape variations upon contact with liquids and temperature changes

Engineering Contradiction:
ImprovestabilityVSAvoidphysical shape stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent applies composite materials by combining conductive polymer particles (providing detection capability) with a solid matrix material (providing structural stability). The conductive polymer particles are dispersed and fixed within the solid matrix, preventing shape variations while maintaining electrical conductivity for marker detection. This composite structure resolves the contradiction between detection functionality and physical stability.

Inventive Principle:
Principle #40Composite materials

2Measurement precision

If bulky equipment is used to detect markers, then detection precision is improved, but device complexity and portability worsen

Engineering Contradiction:
Improvemarker detection precisionVSAvoidequipment bulkiness
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical/bulky detection equipment with a simplified electrical measurement system. Instead of using large spectral analyzers or color detectors, the invention uses a simple resistivity tester to measure electrical resistance changes of the conductive polymer particles. This substitution maintains detection precision while dramatically reducing device complexity and enabling portability.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent extracts the essential detection function from complex equipment by isolating the marker detection capability into a specific interaction between conductive polymer particles and marker molecules. This extracted function can be measured with simple electrical resistance measurements, removing the need for bulky analytical equipment while preserving detection precision.

Inventive Principle:
Principle #2Taking out (Extraction)

3Reliability

If markers are present in low concentrations, then authentication security is improved, but detection difficulty increases

Engineering Contradiction:
Improveauthentication securityVSAvoidmarker detection difficulty
Core Design Contradiction:
ReliabilityVSDifficulty of detecting and measuring

Solution Approach 1:

The patent uses parameter changes by measuring electrical resistance, which changes in response to marker concentration. The conductive polymer particles exhibit resistance variations that correlate with marker presence and concentration, enabling detection of low concentration markers through sensitive electrical measurements without requiring complex instrumentation.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables rapid and reliable detection of markers in fuels, providing a higher security level than conventional methods by distinguishing between different markers and concentrations, and is easy to implement, even for untrained users.

Implementation Method 1

the marker is capable of undergoing a chemical reaction and/or a doping/de-doping process with the polymer with variable conductivity present in the polymer formulation, to thereby cause a change in the conductivity or resistivity of the polymer formulation

Methodology Applied
Scientific EffectDoping/De-doping:

Implementation Method 2

a section equipped with heater element for heating the liquid to be tested up to a temperature where a significant fraction of the one or more markers in the liquid evaporates

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentEP3201615B1Detection device to identify markers dissolved in a liquid, system comprising the device, detection method and method for manufacturing the device
Publication Date: 2020.04.15 SICPA HOLDING SA
  • EP3201615B1 patent drawingFigure 1~2
  • EP3201615B1 patent drawingFigure 3~4
  • EP3201615B1 patent drawingFigure 5~6

AI summary

A detection device for detecting a marker in a liquid, preferably a fuel, comprising: a reaction chamber 5, provided with a de-dopable conductive polymer 6 building a path between two conductive pads 10 connected to a resistivity measurement device, wherein the de-dopable conductive polymer 6 is able to be de-doped by a chemical reaction with the marker, changing its resistivity.