Polymer Interlayer Color Compensation

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Solution Overview

Problem

Current polymer interlayers for laminated safety glass often exhibit undesirable yellow color due to manufacturing processes and additives, which affects their optical quality and aesthetic appeal, particularly in applications requiring clear or extra clear glazing.

Innovation Solution

Incorporating specific colorants into poly(vinyl butyral) resin and plasticizer formulations to adjust the a* and b* color coordinates, resulting in interlayers with a yellowness index (YI) of 0<YI<2, achieving a more neutral or crystal-clear appearance without compromising mechanical or optical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If organic compounds and additives are added to the interlayer formulation during manufacturing, then the interlayer gains necessary functional properties, but the interlayer develops undesirable yellow color

Engineering Contradiction:
Improvefunctional properties of interlayerVSAvoidyellow color of interlayer
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies color compensation by adding blue colorants (such as ultramarine blue, cobalt blue, or phthalocyanine blue) to counteract the yellow color generated by organic compounds and additives. The blue colorant absorbs yellow light wavelengths and reflects blue wavelengths, creating a visual neutralization effect that masks the yellow discoloration while preserving the functional properties of the interlayer formulation.

Inventive Principle:
Principle #32Color changes

Solution Approach 2:

The patent creates a composite interlayer formulation that combines multiple components: the base polymer (polyvinyl butyral), functional additives (plasticizers, stabilizers, adhesion promoters), and color compensating agents (blue pigments or dyes). This composite approach allows the interlayer to maintain all necessary functional properties while the blue colorant compensates for the yellowing effect, achieving a balanced formulation that satisfies both performance and aesthetic requirements.

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If stabilizers and optical brighteners are added to reduce yellowness, then the yellow color is partially reduced, but the formulation complexity and manufacturing difficulty increase

Engineering Contradiction:
Improveyellowness of interlayerVSAvoidformulation complexity
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The patent simplifies the approach by changing the color compensation parameter from using multiple functional additives (stabilizers, brighteners) to using a single or limited combination of blue colorants. By adjusting the concentration and type of blue pigment or dye, the formulation achieves yellow color reduction without significantly increasing formulation complexity or manufacturing difficulty. This parameter change approach maintains formulation simplicity while effectively addressing the yellowness issue.

Inventive Principle:
Principle #35Parameter changes

3Object-generated harmful factors

If manufacturing process modifications are made to limit component contributions to yellowness, then yellow color is reduced, but production time and process complexity increase

Engineering Contradiction:
Improveyellow color of interlayerVSAvoidmanufacturing time
Core Design Contradiction:
Object-generated harmful factorsVSLoss of time

Solution Approach 1:

The patent applies preliminary action by pre-selecting and pre-mixing blue colorants into the interlayer formulation before the extrusion process. This allows the color compensation to occur during normal manufacturing operations rather than requiring additional post-processing steps or extended manufacturing time. The blue colorant is incorporated in advance, so the yellow color reduction happens automatically during standard production without adding significant time or process complexity.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces the yellowness of polymer interlayers, enhancing their aesthetic appeal and optical quality, making them suitable for applications requiring low color or crystal-clear glazing without sacrificing performance.

Implementation Method 1

Incorporating specific colorants into poly(vinyl butyral) resin and plasticizer formulations to adjust the a* and b* color coordinates, resulting in interlayers with a yellowness index (YI) of 0<YI<2

Methodology Applied
Scientific EffectColor absorption and reflection:

Data Source

PatentUS20210394492A1Polymer interlayers having reduced color
Publication Date: 2021.12.23 SOLUTIA INC
  • US20210394492A1 patent drawing
  • US20210394492A1 patent drawing

AI summary

Polymer interlayers that have low color for multiple layer panels are disclosed. The use of polymer interlayers having low color provide multiple layer panels with low color and lower yellowness index.