Polymer Latex Cementing Fluid for Wellbore Integrity

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Solution Overview

Problem

Current cementing fluids in wellbore operations face challenges such as fluid channeling, formation of micro-annuli, and filtration losses, which affect well integrity and production efficiency.

Innovation Solution

A polymer-based cementing fluid composition is developed, incorporating a latex with polyvinyl alcohol and styrene-butadiene polymers, along with calcium oxide, silicon dioxide, aluminum oxide, and gypsum, which forms a stable aqueous colloidal dispersion to reduce fluid losses and improve viscosity, thereby enhancing wellbore integrity and production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional cementing fluids are used, then the cementing process can be performed, but fluid channeling and micro-annuli formation occur reducing well integrity

Engineering Contradiction:
Improvewell integrityVSAvoidfluid channeling and micro-annuli formation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces a polymer-based latex additive as an intermediary substance in the cementing fluid composition. This latex forms a thin-film barrier that acts as a mediator between the cement slurry and formation fluids, preventing direct interaction that causes channeling and micro-annuli. The latex particles distribute throughout the cement slurry and create a flexible sealing layer that accommodates stress variations while maintaining well integrity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite cementing fluid by combining traditional cement materials (calcium oxide, silicon dioxide, aluminum oxide, gypsum) with polymer-based latex components. This composite formulation integrates the binding and structural properties of cement with the sealing and flexibility properties of the polymer latex, resulting in a material that simultaneously provides structural support and prevents fluid leakage pathways.

Inventive Principle:
Principle #40Composite materials

2Reliability

If cementing fluid is introduced to provide hydraulic seal, then zone isolation is established, but filtration losses occur reducing production efficiency

Engineering Contradiction:
Improvezone isolationVSAvoidfiltration losses
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The polymer-based latex in the cementing fluid forms a flexible thin-film barrier within the cement slurry. This thin film acts as a selective barrier that prevents filtration losses by blocking fluid pathways through the cement matrix while maintaining the hydraulic seal for zone isolation. The flexibility of the polymer film allows it to conform to formation irregularities and maintain sealing effectiveness under varying stress conditions.

Inventive Principle:
Principle #30Flexible shells and thin films

3Ease of operation

If cementing fluid composition is optimized for viscosity, then mixing ability improves, but complexity of formulation increases

Engineering Contradiction:
Improvemixing ability of cement slurriesVSAvoidformulation complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent optimizes specific parameters of the polymer-based latex including molecular weight, composition ratios (styrene 20-30%, butadiene 70-80%, carboxylic acid 1-5%), and concentration in the cementing fluid (1-15 wt%). By carefully controlling these parameters, the formulation achieves improved mixing ability and rheological properties without requiring excessively complex formulation approaches. The defined parameter ranges provide a systematic method for optimizing performance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The polymer-based cementing fluid composition effectively reduces fluid channeling, micro-annuli formation, and filtration losses, improving wellbore integrity and production efficiency by forming a thin-film barrier and enhancing the mixing ability of cement slurries.

Implementation Method 1

incorporating a latex with polyvinyl alcohol and styrene-butadiene polymers, along with calcium oxide, silicon dioxide, aluminum oxide, and gypsum, which forms a stable aqueous colloidal dispersion

Methodology Applied
Scientific EffectColloidal dispersion: Colloid

Implementation Method 2

effectively reduces fluid channeling, micro-annuli formation, and filtration losses, improving wellbore integrity and production efficiency by forming a thin-film barrier

Methodology Applied
Scientific EffectThin-film barrier formation: Thin Films

Data Source

PatentUS11713410B1Polymer-based latex for cementing fluids
Publication Date: 2023.08.01 SAUDI ARABIAN OIL CO
  • US11713410B1 patent drawing
  • US11713410B1 patent drawing
  • US11713410B1 patent drawing

AI summary

A cementing fluid composition includes a latex and a cement. The latex includes a first polymer and a second polymer. The first polymer includes polyvinyl alcohol and polyvinyl acetate. A molar concentration of the polyvinyl alcohol in the first polymer is greater than 80% and less than 100%. The second polymer has a general structure in which x is an overall molar ratio of styrene, y is an overall molar ratio of butadiene, and z is an overall molar ratio of carboxylic acid. A sum of x, y, and z is represented as s. Styrene (x) is in a range of from about 20% to about 30% of s. Butadiene (y) is in a range of from about 70% to about 80% of s. Carboxylic acid (z) is in a range of from about 1% to about 5% of s.