Polymer Matrix Aerosol Element for Nicotine Encapsulation

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Solution Overview

Problem

Existing aerosol-generating substrates face challenges in encapsulating nicotine formulations due to hydrophilic aerosol formers like glycerin and propylene glycol, leading to instability, leakage, and degradation issues, especially when heated, which affects the sensory profile and efficiency of aerosol delivery.

Innovation Solution

A solid continuous matrix structure comprising a polymer matrix with a high content of polyhydric alcohol, such as glycerin, traps the nicotine formulation, allowing for controlled release upon heating, minimizing encapsulation material and maintaining stability and geometric integrity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If hydrophilic encapsulation materials are used to encapsulate nicotine formulation, then stability and containment are improved, but aerosol former payload is insufficient due to high material requirements

Engineering Contradiction:
Improveencapsulation stabilityVSAvoidnicotine formulation payload
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The invention uses a composite encapsulation system combining a hydrophilic polymer matrix (such as gelatin or alginate) with a hydrophobic coating layer (such as shellac or ethyl cellulose). This composite structure allows the hydrophilic material to provide stability and containment while the hydrophobic layer prevents excessive material consumption, thereby maintaining high nicotine formulation payload.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention changes the physical and chemical parameters of the encapsulation system by controlling the molecular weight, concentration, and cross-linking degree of the hydrophilic polymer. These parameter adjustments optimize the balance between encapsulation stability and payload capacity, reducing the amount of material needed while maintaining effectiveness.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If hydrophobic encapsulation materials are used to encapsulate nicotine formulation, then material efficiency is improved, but thermal degradation occurs at processing and operating temperatures

Engineering Contradiction:
Improveencapsulation material usageVSAvoidencapsulation material stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The invention combines hydrophobic coating materials with low thermal stability requirements with hydrophilic polymer matrices that can withstand processing temperatures. The hydrophobic layer provides material efficiency while the hydrophilic matrix maintains structural integrity at elevated temperatures, preventing degradation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention applies different material properties to different regions of the encapsulation structure. The inner hydrophilic matrix provides thermal stability during processing, while the outer hydrophobic coating provides material efficiency and controlled release properties, with each layer optimized for its specific function.

Inventive Principle:
Principle #3Local quality

3Productivity

If high polyhydric alcohol content is used in aerosol-generating formulation, then aerosol generation efficiency is improved, but leakage and instability increase

Engineering Contradiction:
Improveaerosol generation efficiencyVSAvoidformulation stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention uses a composite formulation system where polyhydric alcohols (such as glycerin and propylene glycol) are combined with nicotine salts and flavoring agents in specific ratios. This composite formulation maintains high aerosol generation efficiency while the balanced composition prevents leakage and instability issues.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention optimizes the concentration parameters of polyhydric alcohols within specific ranges (e.g., glycerin at 20-40% and propylene glycol at 10-30%) to achieve the optimal balance between aerosol generation efficiency and formulation stability, preventing both leakage and insufficient performance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a stable and efficient aerosol delivery with minimal leakage and adverse effects on the sensory profile, allowing for higher nicotine content and improved handling and manufacturing of aerosol-generating articles, with efficient heat utilization and controlled aerosol generation between 150°C to 350°C.

Implementation Method 1

an aerosol is generated by the transfer of heat from a heat source to a physically separate aerosol-generating substrate or material

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Implementation Method 2

During use of the aerosol-generating article, volatile compounds are released from the aerosol-generating substrate by heat transfer from the heat source and are entrained in air drawn through the aerosol-generating article. As the released compounds cool, they condense to form an aerosol.

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 3

volatile compounds are released from the aerosol-generating substrate by heat transfer from the heat source

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 4

volatile compounds are released from the aerosol-generating substrate by heat transfer from the heat source and are entrained in air drawn through the aerosol-generating article

Methodology Applied
Scientific EffectEntrainment: Entrainment

Implementation Method 5

As the released compounds cool, they condense to form an aerosol

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentUS20220361557A1Aerosol-generating element for use in an aerosol-generating article or system
Publication Date: 2022.11.17 PHILIP MORRIS PRODUCTS SA
  • US20220361557A1 patent drawing

AI summary

An aerosol-generating element for an aerosol-generating article or system is provided, the aerosol-generating element including: a solid continuous matrix structure; and an aerosol-generating formulation dispersed within the structure, in which the formulation is trapped within the structure and releasable from the structure upon heating of the aerosol-generating element, in which the structure is a polymer matrix including one or more matrix-forming polymers, in which the formulation dispersed within the structure includes at least one alkaloid or cannabinoid compound and a polyhydric alcohol, in which a polyhydric alcohol content in the formulation dispersed within the structure accounts for at least 30 percent by weight based on a total weight of the aerosol-generating element, and in which the aerosol-generating element has an equivalent diameter of at least about 0.5 millimetres and an ovality from about 2 percent to about 30 percent.