Dry End Polymer Coating for Paper Strength
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Solution Overview
Problem
The paper industry faces challenges in enhancing the dry strength of recycled fiber papers, as traditional wet end strength additives reach a performance plateau and can interfere with fiber quality and machine operations, while surface applied additives require stable solutions to prevent precipitation or viscosity issues.
Innovation Solution
A stable dry strength composition comprising a nearly neutral acrylamide polymer, a cationic polymer prepared from monomers with amine functionality, and starch, applied to formed paper substrates to enhance dry strength without viscosity buildup or gel formation, allowing for improved dry strength without interfering with paper machine operations.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Strength
If wet end strength additives are used to improve paper strength, then paper strength is improved, but interference with fiber quality and machine operations occurs
Solution Approach 1:
The patent applies strength additives at the dry end of the papermaking process after sheet formation has occurred, rather than at the wet end during fiber suspension. This preliminary action (applying after formation) allows the additives to bond to formed fibers without interfering with fiber quality, machine drainage, or operational processes that occur during wet end papermaking.
Solution Approach 2:
The patent extracts the strength enhancement function from the wet end process and separates it into a distinct dry end application step. By taking out the strength additive application from the wet end fiber suspension process, the harmful interferences with fiber quality and machine operations are eliminated while preserving the beneficial paper strength improvement.
2Strength
If surface applied additives are used to enhance dry strength, then dry strength is improved, but solution stability issues such as precipitation and viscosity buildup occur
Solution Approach 1:
The patent employs a composite additive system comprising multiple components: a cationic polymer (such as polydiallyldimethylammonium chloride), an acrylamide polymer, and optionally a starch component. This composite material approach creates synergistic interactions between components that enhance dry strength while the specific composition ratios and molecular characteristics maintain solution stability, preventing precipitation and excessive viscosity buildup during application.
Solution Approach 2:
The patent optimizes specific parameters of the additive components including charge density, molecular weight, and composition ratios. By carefully controlling these parameters (e.g., using cationic polymers with specific charge densities and acrylamide polymers with controlled molecular weights), the system achieves both improved dry strength and maintained solution stability, avoiding precipitation and viscosity issues that plague other surface applied additives.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The composition effectively enhances the dry strength of paper substrates, providing improved bursting and compression strength, and can be applied at the dry end of the papermaking process, overcoming the limitations of traditional additives by maintaining solution stability and preventing operational issues.
Implementation Method 1
a stable blend of one or more polymers, at least one of which may be a charged polymer
Implementation Method 2
enhanced hydrogen bonding between cellulose fiber and the polymer chain
Implementation Method 3
The composition effectively enhances the dry strength of paper substrates, providing improved bursting and compression strength
Data Source
AI summary
Stable, coating compositions useful for enhancing the dry strength of paper are disclosed. The compositions comprise an aqueous solution of nearly neutral polyacrylamide, cationic polymer and starch. Method of using the coating composition to enhance the diy strength of paper is also disclosed.