Polymer Nanostructure Conditioning via Phonon Induction

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Solution Overview

Problem

Polymers used in power-dense electrical machinery face challenges in withstanding thermal expansion stresses, core dimensional distortions, high-frequency vibrations, and Lorentz forces, leading to potential cracking or delamination, while also requiring improved voltage stand-off and mechanical resilience.

Innovation Solution

The method involves inducing optical or acoustic phonons into polymeric materials using alternating electric fields or dynamic mechanical fields, promoting nanostructural modifications such as adapting local environments of polar groups, reducing density fluctuations, and achieving nano-phase separation, which enhances the polymer's toughness and voltage endurance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If polymers are used in power-dense electrical machinery, then voltage stand-off and elasticity are provided, but the polymer cracks or delaminates under thermal expansion stresses, core dimensional distortions, high frequency vibrations, and Lorentz forces

Engineering Contradiction:
Improvevoltage stand-off capabilityVSAvoidresistance to mechanical stress
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies composite materials by combining polymeric insulation with dispersed particulate materials (such as silica, alumina, or other inorganic particles) to create a composite polymer system. This composite structure provides both the voltage stand-off capability of the polymer and the mechanical strength of the particulate reinforcement, resolving the contradiction between electrical insulation performance and mechanical stress resistance. The particulate dispersion within the polymer matrix creates a hybrid material that leverages the advantages of both components.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs parameter changes by modifying the physical and chemical properties of the polymer through controlled processing conditions. Specifically, the patent controls crosslinking density, molecular weight, and compositional ratios to optimize the balance between electrical insulation properties and mechanical strength. By adjusting these parameters, the polymer can simultaneously achieve high voltage stand-off capability and enhanced resistance to thermal expansion and mechanical stress.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If the polymeric matrix material provides elasticity to the machine environment, then the polymer can respond to cyclic mechanical stress, but it is susceptible to cracking and delamination under high stress conditions

Engineering Contradiction:
Improveresponse to cyclic mechanical stressVSAvoidresistance to cracking and delamination
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent applies preliminary action by pre-reinforcing the polymer matrix with dispersed particulate materials before the polymer is subjected to service conditions. This pre-reinforcement creates a more robust structure that is better prepared to withstand cyclic mechanical stresses, thermal expansion, and Lorentz forces. The particulate dispersion is incorporated during manufacturing to establish enhanced mechanical integrity before the polymer encounters operational stresses that would otherwise cause cracking or delamination.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses parameter changes by modifying the crosslinking density and molecular structure of the polymer to enhance its toughness and resistance to cracking. By controlling the crosslinking degree and molecular weight distribution, the polymer achieves optimal elasticity for responding to cyclic stresses while simultaneously improving its resistance to cracking and delamination under high stress conditions.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This treatment improves the polymer's toughness, density, and voltage endurance, reducing water absorption and increasing breakdown strength, thus addressing the limitations of existing polymers in high-stress electrical insulation applications.

Implementation Method 1

inducing optical or acoustic phonons into the material. The inducing is performed by application of an alternating electric field or a dynamic mechanical field

Methodology Applied
Scientific EffectPhonon induction:

Implementation Method 2

inducing optical or acoustic phonons into the material. The inducing is performed by application of an alternating electric field or a dynamic mechanical field

Methodology Applied
Scientific EffectPhonon induction:

Data Source

PatentUS20230192977A1Dynamic field conditioning of polymer nano-structure
Publication Date: 2023.06.22 THE UNITED STATES OF AMERICA AS REPRESENTED BY THE SECRETARY OF THE NAVY
  • US20230192977A1 patent drawing
  • US20230192977A1 patent drawing
  • US20230192977A1 patent drawing

AI summary

A method of: providing a polymeric material, and inducing optical or acoustic phonons into the material. The inducing is performed by application of an alternating electric field or a dynamic mechanical field. When the method is performed on a polyepoxy thermoset, this may result in a water absorption rate of no more than 0.1 wt. % per 24 hours.