Polymer-Stabilized Liquid Crystal Medium for Fast Response

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Solution Overview

Problem

Current liquid-crystalline display technologies face challenges in achieving high specific resistance, short response times, and low threshold voltage for producing grey shades, especially in VA displays, which also suffer from viewing-angle dependence and image sticking issues, while existing LC mixtures lack long-term stability and adequate dielectric anisotropy.

Innovation Solution

A liquid-crystalline medium comprising at least two polymerisable compounds and one compound with negative dielectric anisotropy, which allows for the formation of a polymer layer replacing the top glass substrate, improving response times and stability, and featuring a broad nematic phase range and low rotational viscosity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If conventional liquid-crystalline mixtures are used in VA displays, then the display structure is simple, but the response times are slow and image sticking occurs

Engineering Contradiction:
Improveresponse timeVSAvoiddisplay structure
Core Design Contradiction:
SpeedVSDevice complexity

Solution Approach 1:

A polymer layer is formed in advance within the liquid-crystalline medium before the display operates. This pre-formed polymer network provides mechanical support and stabilizes the liquid crystal alignment, enabling faster response times and preventing image sticking without requiring additional structural components.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The liquid-crystalline medium is formulated as a composite containing both liquid-crystalline compounds and polymerisable compounds. When UV irradiated, the polymerisable compounds form a polymer network embedded within the liquid crystal matrix, creating a composite material that combines the fast response characteristics of liquid crystals with the structural stability of polymers.

Inventive Principle:
Principle #40Composite materials

2Reliability

If liquid-crystalline mixtures with high specific resistance are used, then reliability improves, but threshold voltage increases making grey shade production difficult

Engineering Contradiction:
Improvespecific resistance stabilityVSAvoidthreshold voltage
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The liquid-crystalline mixture is formulated with specific compounds and ratios (including chiral dopants at 0.01-5 wt%) that optimize the balance between dielectric anisotropy and viscosity. This parameter optimization enables high specific resistance stability while maintaining threshold voltage within acceptable ranges for grey shade control.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed LC mixture enhances response times, stability, and reliability, reducing image sticking and improving transmittance, while maintaining high specific resistance and low threshold voltage, suitable for various display applications including TVs and monitors.

Implementation Method 1

Media of this type can be used, in particular, for electro-optical displays having active-matrix addressing based on the ECB effect and for IPS (in-plane switching) displays or FFS (fringe field switching) displays

Methodology Applied
Scientific EffectElectro-optical effect: Electro-Optic Effects

Implementation Method 2

The principle of electrically controlled birefringence, the ECB effect or also DAP (deformation of aligned phases) effect

Methodology Applied
Scientific EffectElectrically controlled birefringence: Birefringence

Implementation Method 3

The liquid-crystalline medium according to the invention contains at least two polymerisable compounds

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentEP2817388B1Liquid crystalline medium
Publication Date: 2020.03.25 MERCK PATENT GMBH
  • EP2817388B1 patent drawingFigure 1
  • EP2817388B1 patent drawing
  • EP2817388B1 patent drawing

AI summary

The invention relates to a liquid-crystalline medium which contains at least two polymerisable compounds or reactive mesogens (RM) and at least one compound selected from the group of compounds of the formula IIA, IIB and IIC, in which R2A, R2B, R2C, L1-6, ring B, Z2, Z2, p, q and v have the meanings indicated in Claim 1, and to the use thereof for an active-matrix display, in particular based on the VA, PSA, PS-VA, PALC, FFS, PS-FFS, IPS or PS-IPS effect, especially for the use in LC displays of the PS (polymer stabilised) or PSA (polymer sustained alignment) type.