Skin Bonding Polymer Stabilizes UV-A Absorbers

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Solution Overview

Problem

Conventional sunscreen compositions, particularly UV-A absorbers like avobenzone, tend to degrade when exposed to light, reducing their effectiveness in protecting the skin from ultraviolet radiation.

Innovation Solution

A sunscreen composition is developed that includes a skin bonding polymer component, specifically a hydrophobic polymer/hydrophilic polymer adduct, which enhances the stability of UV-A absorbers by forming a complex that maintains stability in water and on the skin, thereby prolonging the protection against UV-A radiation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If UV-A absorbers like avobenzone are used in sunscreen compositions, then protection against UV-A radiation is provided, but the UV-A absorbers degrade when exposed to light, reducing their effectiveness

Engineering Contradiction:
Improveeffectiveness of UV-A absorberVSAvoidstability of UV-A absorber
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent uses a skin bonding polymer as an intermediary substance that forms a complex with the UV-A absorber (avobenzone). This polymer complex protects the UV-A absorber from direct light exposure while maintaining its UV-A filtering capability. The polymer acts as a mediator between the UV-A absorber and environmental factors (light, water), reducing degradation and extending the absorber's effectiveness.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite material system consisting of the UV-A absorber combined with the skin bonding polymer. This composite structure (polymer-absorber complex) leverages the stabilizing properties of the polymer to protect the UV-A absorber, while maintaining the sunscreen functionality. The composite approach allows the system to achieve both UV protection and enhanced stability.

Inventive Principle:
Principle #40Composite materials

2Duration of action of moving object

If conventional sunscreen compositions are used, then UV protection is provided, but the protection duration is limited due to degradation of UV-A absorbers

Engineering Contradiction:
Improveduration of UV protectionVSAvoideffectiveness of UV-A absorber
Core Design Contradiction:
Duration of action of moving objectVSReliability

Solution Approach 1:

The skin bonding polymer serves as a mediator that extends the duration of UV protection by protecting the UV-A absorber from degradation. The polymer forms a stable complex that maintains the absorber's effectiveness over time, allowing prolonged protection against UV-A radiation without the rapid decline seen in conventional formulations.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If water-based emulsion is used as carrier, then the composition can be easily applied to skin, but the UV-A absorbers remain exposed to water and light, accelerating degradation

Engineering Contradiction:
Improveease of applicationVSAvoidstability of UV-A absorber
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The skin bonding polymer acts as an intermediary protective layer between the UV-A absorber and the aqueous environment. By forming a complex with the absorber, the polymer shields it from water and light exposure while allowing the formulation to maintain its water-based emulsion structure for easy application. The polymer complex serves as a protective interface that enables both ease of use and stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sunscreen composition effectively binds to the skin for an extended period, maintaining the stability and effectiveness of UV-A absorbers, such as avobenzone, thereby providing prolonged protection against UV-A radiation.

Implementation Method 1

The hydrophobic polymer/hydrophilic polymer adduct comprises: (i) hydrophobic polymer composition comprising a mixture of a lower poly(vinylpyrrolidone/alkylene) polymer wherein the alkylene group contains about 10 to about 24 carbon atoms and a higher poly(vinylpyrrolidone/alkylene) polymer wherein the alkylene group contains greater than about 24 carbon atoms; and (ii) hydrophilic polymer composition comprising carboxylic groups, hydroxylic groups, or both carboxylic groups and hydroxylic groups.

Methodology Applied
Scientific EffectComplex formation:

Implementation Method 2

The sunscreen composition includes a skin bonding polymer composition comprising a hydrophobic polymer/hydrophilic polymer adduct

Methodology Applied
Scientific EffectHydrophobic interaction:

Implementation Method 3

The sunscreen composition effectively binds to the skin for an extended period, maintaining the stability and effectiveness of UV-A absorbers

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 4

Sunscreen agents that primarily filter or absorb UV-A light are often referred to as UV-A absorbers

Methodology Applied
Scientific EffectAbsorption of electromagnetic radiation: Absorption (EM radiation)

Data Source

PatentUS8128913B1Sunscreen composition with enhanced UV-A absorber stability and methods
Publication Date: 2012.03.06 SKINVISIBLE PHARMACEUTICALS INC
  • US8128913B1 patent drawing
  • US8128913B1 patent drawing
  • US8128913B1 patent drawing

AI summary

A sunscreen composition is provided according to the present invention. The sunscreen composition includes a skin bonding polymer composition comprising a hydrophobic polymer/hydrophilic polymer adduct, at least one sunscreen active agent comprising a UV-A absorber, and water in an amount of affected to provide a the composition with the texture suitable for application to skin. The hydrophobic polymer/hydrophilic polymer adduct comprises: (i) hydrophobic polymer composition comprising a mixture of a lower poly(vinylpyrrolidone/alkylene) polymer wherein the alkylene group contains about 10 to about 24 carbon atoms and a higher poly(vinylpyrrolidone/alkylene) polymer wherein the alkylene group contains greater than about 24 carbon atoms; and (ii) hydrophilic polymer composition comprising carboxylic acid groups, hydroxyl groups, or both carboxylic acid groups and hydroxyl groups.