Crosslinkable Polymer Composition for Water Tree Resistance

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Solution Overview

Problem

Current polymer compositions for electric power cables, particularly those based on polyolefins, are prone to water treeing under humid conditions, leading to reduced breakdown strength and potential electrical failure, and existing solutions either compromise on water tree resistance or productivity during the manufacturing process.

Innovation Solution

A crosslinkable polymer composition comprising an unsaturated polyolefin with a high amount of carbon-carbon double bonds and a polar copolymer, which enhances crosslinking properties and resistance to water treeing, while allowing for faster crosslinking and milder crosslinking conditions, thereby improving cable longevity and manufacturing efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If polyethylene is used as insulating material, then good dielectric properties are achieved, but water tree resistance is poor

Engineering Contradiction:
Improvedielectric propertiesVSAvoidwater tree resistance
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent uses a composite material system consisting of polyethylene base polymer combined with vinyl-containing copolymer additives (such as ethylene-vinyl acetate copolymer or ethylene-methyl acrylate copolymer). This composite approach allows the material to maintain the excellent dielectric properties of polyethylene while introducing water tree resistance through the vinyl groups that form crosslinked structures preventing water tree propagation.

Inventive Principle:
Principle #40Composite materials

2Productivity

If crosslinking is performed at high temperature to achieve fast crosslinking, then productivity is improved, but premature decomposition of peroxide occurs

Engineering Contradiction:
Improvecrosslinking speedVSAvoidperoxide stability
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical parameters of the crosslinking system by selecting peroxide compounds with specific decomposition temperatures matched to the processing conditions. It also modifies the thermal parameters by optimizing the crosslinking temperature and time, and introduces vinyl-containing copolymers that enable crosslinking at lower temperatures, thereby preventing premature peroxide decomposition while maintaining fast crosslinking speed.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If peroxide decomposition is avoided during extrusion to prevent scorch, then material homogeneity is maintained, but crosslinking efficiency is reduced

Engineering Contradiction:
ImprovehomogeneityVSAvoidcrosslinking efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent applies local quality control by spatially separating the peroxide decomposition and crosslinking processes. During extrusion, the peroxide remains stable and uniformly distributed without decomposing. The crosslinking reaction is then activated locally in the cable sheath or insulation layer through controlled thermal treatment after extrusion, ensuring both homogeneity during processing and high crosslinking efficiency in the final product.

Inventive Principle:
Principle #3Local quality

4Object-affected harmful factors

If vinyl-containing copolymer is added to improve water tree resistance, then water tree growth is inhibited, but material complexity increases

Engineering Contradiction:
Improvewater tree growth inhibitionVSAvoidmaterial composition complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent merges multiple functions into the vinyl-containing copolymer additive. It simultaneously provides water tree resistance through vinyl group crosslinking, maintains processability during extrusion, and enables controlled crosslinking. By combining these functions in a single copolymer component rather than using multiple separate additives, the material complexity is minimized while achieving the desired performance.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves improved electric breakdown strength after wet ageing and faster crosslinking, enabling longer cable service life and increased productivity without compromising on water tree resistance, thus addressing the limitations of existing solutions.

Implementation Method 1

a crosslinkable polymer composition comprising (i) an unsaturated polyolefin having a total amount of carbon-carbon double bonds/1000 carbon atoms of more than 0.37

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 2

a polar copolymer

Methodology Applied
Scientific EffectPolar interaction: Hydrophile

Data Source

PatentUS8912284B2Polymer composition having improved wet ageing properties
Publication Date: 2014.12.16 BOREALIS TECH OY
  • US8912284B2 patent drawing

AI summary

The present invention relates to a crosslinkable polymer composition, comprising (i) an unsaturated polyolefin having a total amount of carbon-carbon double bonds/1000 carbon atoms of more than 0.37, and (ii) a polar copolymer.