Crosslinkable Polymer Composition for Water Tree Resistance
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Solution Overview
Problem
Current polymer compositions for electric power cables, particularly those based on polyolefins, are prone to water treeing under humid conditions, leading to reduced breakdown strength and potential electrical failure, and existing solutions either compromise on water tree resistance or productivity during the manufacturing process.
Innovation Solution
A crosslinkable polymer composition comprising an unsaturated polyolefin with a high amount of carbon-carbon double bonds and a polar copolymer, which enhances crosslinking properties and resistance to water treeing, while allowing for faster crosslinking and milder crosslinking conditions, thereby improving cable longevity and manufacturing efficiency.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If polyethylene is used as insulating material, then good dielectric properties are achieved, but water tree resistance is poor
Solution Approach 1:
The patent uses a composite material system consisting of polyethylene base polymer combined with vinyl-containing copolymer additives (such as ethylene-vinyl acetate copolymer or ethylene-methyl acrylate copolymer). This composite approach allows the material to maintain the excellent dielectric properties of polyethylene while introducing water tree resistance through the vinyl groups that form crosslinked structures preventing water tree propagation.
2Productivity
If crosslinking is performed at high temperature to achieve fast crosslinking, then productivity is improved, but premature decomposition of peroxide occurs
Solution Approach 1:
The patent changes the chemical parameters of the crosslinking system by selecting peroxide compounds with specific decomposition temperatures matched to the processing conditions. It also modifies the thermal parameters by optimizing the crosslinking temperature and time, and introduces vinyl-containing copolymers that enable crosslinking at lower temperatures, thereby preventing premature peroxide decomposition while maintaining fast crosslinking speed.
3Manufacturing precision
If peroxide decomposition is avoided during extrusion to prevent scorch, then material homogeneity is maintained, but crosslinking efficiency is reduced
Solution Approach 1:
The patent applies local quality control by spatially separating the peroxide decomposition and crosslinking processes. During extrusion, the peroxide remains stable and uniformly distributed without decomposing. The crosslinking reaction is then activated locally in the cable sheath or insulation layer through controlled thermal treatment after extrusion, ensuring both homogeneity during processing and high crosslinking efficiency in the final product.
4Object-affected harmful factors
If vinyl-containing copolymer is added to improve water tree resistance, then water tree growth is inhibited, but material complexity increases
Solution Approach 1:
The patent merges multiple functions into the vinyl-containing copolymer additive. It simultaneously provides water tree resistance through vinyl group crosslinking, maintains processability during extrusion, and enables controlled crosslinking. By combining these functions in a single copolymer component rather than using multiple separate additives, the material complexity is minimized while achieving the desired performance.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The composition achieves improved electric breakdown strength after wet ageing and faster crosslinking, enabling longer cable service life and increased productivity without compromising on water tree resistance, thus addressing the limitations of existing solutions.
Implementation Method 1
a crosslinkable polymer composition comprising (i) an unsaturated polyolefin having a total amount of carbon-carbon double bonds/1000 carbon atoms of more than 0.37
Implementation Method 2
a polar copolymer
Data Source
AI summary
The present invention relates to a crosslinkable polymer composition, comprising (i) an unsaturated polyolefin having a total amount of carbon-carbon double bonds/1000 carbon atoms of more than 0.37, and (ii) a polar copolymer.
