Polymer Refractive X-ray Optics via Two-Photon Polymerization

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Solution Overview

Problem

Current methods for fabricating refractive X-ray optics, such as compound refractive lenses and kinoform lenses, suffer from sub-optimal optical performance due to surface roughness and incoherent scattering, limited flexibility in operating with different X-ray beam energies, and require bulky and expensive transfocator devices.

Innovation Solution

The method involves using multiphoton polymerization lithography (MPPL) to fabricate refractive optical elements with surface roughness less than 100 nanometers, enabling the creation of high-resolution, diffraction-limited optics that can be fabricated on a single chip, including compound refractive lenses, kinoform lenses, and transfocators-on-a-chip, allowing for flexible focusing and operation across various X-ray energies.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If top-down pressing and molding techniques are used to fabricate compound refractive lenses, then the manufacturing process is simple and cost-effective, but the surface roughness is poor and optical performance is sub-optimal

Engineering Contradiction:
Improvesurface roughnessVSAvoidfabrication complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent replaces mechanical pressing and molding techniques with a light-based two-photon polymerization process. A femtosecond laser writes the lens structure directly into a photoresist coating on a substrate, eliminating the need for mechanical contact and molds. This substitution of mechanical fabrication with optical fabrication enables atomic-level surface smoothness while maintaining manufacturing accessibility.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If E-beam lithography and deep etching are used to fabricate kinoform lenses, then the surface precision can be improved, but X-ray absorption increases and fabrication complexity increases

Engineering Contradiction:
Improvesurface precisionVSAvoidX-ray absorption
Core Design Contradiction:
Manufacturing precisionVSLoss of energy

Solution Approach 1:

The patent replaces E-beam lithography and deep etching with two-photon polymerization. This optical writing process creates the lens structure without removing material, avoiding the creation of sharp edges and deep trenches that cause X-ray absorption. The polymerized resin structure maintains precision while minimizing energy loss.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent uses a composite structure consisting of a photoresist coating polymerized into lens elements mounted on a substrate. This composite approach allows the optical function to be separated from the mechanical support, enabling the use of low-Z materials in the lens region to minimize X-ray absorption while maintaining structural integrity.

Inventive Principle:
Principle #40Composite materials

3Adaptability or versatility

If traditional refractive optics are used, then the optical performance at a single focal distance is good, but the adaptability to different X-ray beam energies and focal distances is limited

Engineering Contradiction:
Improveenergy flexibilityVSAvoidoptical performance consistency
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent creates dynamically adjustable optics by writing multiple lens elements with different focal lengths into the same photoresist coating. A motorized translation stage allows selective positioning of different lens elements into the beam path, enabling continuous adjustment of focal distance and adaptation to different X-ray energies without changing the physical optics themselves.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent achieves multi-functionality by integrating multiple lens elements with different optical parameters into a single device. The same optical component can serve multiple functions by translating between different focal lengths and energy ranges, eliminating the need for separate optics for each application.

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Adaptability or versatility

If transfocator devices are used to provide flexibility for different focal distances, then the adaptability is improved, but the device size increases and cost increases

Engineering Contradiction:
Improvefocal distance flexibilityVSAvoiddevice size
Core Design Contradiction:
Adaptability or versatilityVSVolume of moving object

Solution Approach 1:

The patent merges multiple lens elements into a single integrated optical component written in one photoresist coating. The motorized translation stage provides the only moving part, combining the functions of multiple discrete lenses and their mounting mechanisms into one compact device. This dramatically reduces the overall volume compared to traditional transfocator assemblies.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent uses a thin photoresist coating (typically 10-50 micrometers) as the optical element, which is much thinner than traditional lens assemblies. This thin-film approach, combined with the motorized translation mechanism, creates a compact transfocator that fits within tight beamline spaces while providing full focal distance adjustment.

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in high-quality, compact, and cost-effective refractive optics with improved surface smoothness and printing resolution, achieving diffraction-limited performance and enabling efficient alignment and tuning of X-ray beam focusing across a range of energies.

Implementation Method 1

providing radiation to a portion of the resin, the radiation configured to cause two photon polymerization of the resin to cause the formation of a first surface of a polymer refractive optical element from the resin

Methodology Applied
Scientific EffectTwo-photon polymerization: Photopolymerisation

Data Source

PatentUS11919264B2Method of printing and implementing refractive X-ray optical components
Publication Date: 2024.03.05 UCHICAGO ARGONNE LLC
  • US11919264B2 patent drawing
  • US11919264B2 patent drawing
  • US11919264B2 patent drawing

AI summary

A method of fabricating a refractive optical element on a substrate may provide less expensive and more compact optics for an X-ray system. The method includes coating the substrate with a resin and providing radiation to a portion of the resin to cause two photon polymerization of the resin. The method further includes forming, by two photon polymerization, a first surface of a polymer refractive optical element from the resin. The first surface is disposed along an optical axis of the refractive optical element and the first surface has a roughness of less than 100 nanometers. Further, the method includes forming, by two photon polymerization, a second surface of the polymer refractive optical element. The second surface is disposed along the optical axis of the refractive optical element and the second surface has a roughness of less than 100 nanometers.