Polymeric Hollow Fiber Membrane Sonication for Fouling Control

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Solution Overview

Problem

Existing methods for manufacturing polymeric membranes face challenges in independently controlling the incorporation of additives, leading to equipment buildup and inefficiencies in membrane formation, hollow fiber collapse during drying, and increased downtime for cleaning.

Innovation Solution

The use of sonication during various stages of the membrane formation process, including the spinning block, precipitation bath, washing bath, and drying chamber, to enhance mixing, reduce additive accumulation, and prevent equipment fouling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If additives are added to spin mass to improve membrane properties, then membrane performance is enhanced, but equipment buildup and fouling occur

Engineering Contradiction:
Improvemembrane performanceVSAvoidequipment buildup
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies ultrasonic vibration (sonication) to the spin mass solution before and during the membrane formation process. This mechanical vibration prevents additive accumulation on equipment surfaces by creating cavitation effects that disrupt material buildup, while simultaneously improving mixing homogeneity of the spin mass components.

Inventive Principle:
Principle #18Mechanical vibration

2Manufacturing precision

If slow precipitation is used to improve membrane morphology, then membrane structure quality is enhanced, but production time increases

Engineering Contradiction:
Improvemembrane morphologyVSAvoidproduction time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent employs periodic ultrasonic treatment during the precipitation process. The ultrasonic waves are applied in cycles that promote controlled phase separation and polymer aggregation, achieving desirable membrane morphology while reducing the overall precipitation time compared to conventional slow precipitation methods.

Inventive Principle:
Principle #19Periodic action

3Productivity

If continuous manufacturing is maintained to improve productivity, then output increases, but equipment cleaning downtime is required

Engineering Contradiction:
Improvemanufacturing outputVSAvoidcleaning downtime
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The patent implements continuous ultrasonic treatment throughout the membrane formation process, preventing additive buildup on equipment surfaces during continuous operation. This eliminates the need for periodic shutdowns for cleaning, maintaining continuous productivity while preventing fouling accumulation.

Inventive Principle:
Principle #20Continuity of useful action

4Stability of the object's composition

If ultrasonic treatment is applied to improve mixing, then component incorporation is enhanced, but energy consumption increases

Engineering Contradiction:
Improvemixing homogeneityVSAvoidenergy consumption
Core Design Contradiction:
Stability of the object's compositionVSUse of energy by moving object

Solution Approach 1:

The patent applies ultrasonic treatment at specific critical stages of the membrane formation process rather than continuously throughout. By targeting key moments when mixing and phase separation occur, the patent achieves sufficient homogeneity with reduced total energy input compared to continuous ultrasonic treatment.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Sonication improves membrane formation by reducing equipment buildup, minimizing downtime, and enhancing the properties of the membrane, such as reducing hollow fiber collapse and improving mixing of components.

Implementation Method 1

utilizing or applying sonication to one or more of the following steps or areas of the membrane formation process: the solution

Methodology Applied
Scientific EffectUltrasonic vibration: Ultrasonic Vibration

Implementation Method 2

reduces or avoids fouling or buildup of the equipment used for polymeric membrane manufacturing

Methodology Applied
Scientific EffectAcoustic cavitation: Acoustic Cavitation

Data Source

PatentUS12409420B2Polymeric membrane and methods for the production of same
Publication Date: 2025.09.09 FRESENIUS MEDICAL CARE HOLDINGS INC
  • US12409420B2 patent drawing
  • US12409420B2 patent drawing
  • US12409420B2 patent drawing

AI summary

The present invention relates to a method to make polymeric membranes that are preferably useful in dialysis, wherein the method conducts at least one membrane-forming step and/or post-forming processing step with the use of sonication. Polymeric membrane, such as polymeric hollow fiber membrane, having improved one or properties are further described.