Polymeric Sorbent Air Filters for Reactive Gas Removal

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Solution Overview

Problem

Current air filtration technologies are inadequate in effectively removing reactive gases such as acid gases from the air, particularly those containing halogen, nitrogen, or sulfur atoms, due to limitations in sorbent materials and filtration mechanisms.

Innovation Solution

Development of air filters utilizing polymeric sorbent particles formed from a divinylbenzene/maleic anhydride precursor material covalently attached with nitrogen-containing compounds, which are supported by various filter structures to capture and retain reactive gases efficiently.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional filtration materials are used, then the filter structure is simple and easy to manufacture, but the ability to remove reactive gases is insufficient

Engineering Contradiction:
Improvereactive gas removal capabilityVSAvoidsorbent material complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses composite polymeric sorbent particles made from divinylbenzene and maleic anhydride precursors, creating a material that combines the structural stability of crosslinked polymers with the reactive functionality of anhydride groups. This composite structure enables effective reactive gas removal while maintaining manufacturability through established polymerization processes

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical parameters of the sorbent material by introducing nitrogen-containing compounds that covalently attach to the polymeric structure. This chemical modification changes the sorbent's affinity and selectivity for reactive gases, dramatically improving removal capability without requiring complex device architecture

Inventive Principle:
Principle #35Parameter changes

2Reliability

If sorbent capacity is increased to improve gas removal, then the filtration effectiveness improves, but the cost and complexity of the filter increases

Engineering Contradiction:
Improvegas removal effectivenessVSAvoidfilter manufacturing simplicity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent employs porous polymeric sorbent particles that provide high surface area and internal volume for gas sorption. The porous structure increases the effective capacity of the sorbent material, allowing robust reactive gas removal while maintaining reasonable material loading and filter thickness

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

By chemically modifying the polymeric precursor with nitrogen-containing compounds, the patent enhances the sorbent's chemical affinity for reactive gases. This parameter change in chemical functionality increases sorption capacity without requiring proportional increases in material quantity or filter complexity

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The air filters demonstrate enhanced capability in removing reactive gases, with the polymeric sorbent particles effectively sorbing acid gases and maintaining their capacity over time, as evidenced by breakthrough curves, thereby improving air quality.

Implementation Method 1

polymeric sorbent particles formed from a divinylbenzene/maleic anhydride precursor material covalently attached with nitrogen-containing compounds, which are supported by various filter structures to capture and retain reactive gases efficiently

Methodology Applied
Scientific EffectChemical adsorption: Adsorption

Data Source

PatentEP3429725B1Air filters comprising polymeric sorbents for reactive gases
Publication Date: 2021.07.07 3M INNOVATIVE PROPERTIES CO
  • EP3429725B1 patent drawingFigure 1~3
  • EP3429725B1 patent drawingFigure 4~5
  • EP3429725B1 patent drawingFigure 6~7

AI summary

An air filter including a filter support that supports polymeric sorbent particles. The polymeric sorbent is the reaction product of a divinylbenzene/maleic anhydride precursor polymeric material with a nitrogen-containing compound. The air filter may be used for capturing e.g. reactive gases.