Polymerizable Compound for Uniform Polarized Light Conversion

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Solution Overview

Problem

Existing retardation films in flat panel displays face challenges in achieving uniform polarized light conversion over a wide wavelength band due to wavelength dispersion, high melting points of low-molecular-weight polymerizable compounds, and high production costs.

Innovation Solution

A polymerizable compound represented by formula (I) is used to produce a polymerizable composition that includes an initiator, resulting in a polymer with a low melting point, excellent solubility, and the ability to create an optical film with uniform polarized light conversion across a wide wavelength band at a lower cost.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Length of stationary object

If a low-molecular-weight polymerizable compound is used to reduce film thickness, then the retardation film thickness can be reduced, but the melting point becomes too high for industrial processing

Engineering Contradiction:
Improveretardation film thicknessVSAvoidmelting point
Core Design Contradiction:
Length of stationary objectVSTemperature

Solution Approach 1:

The patent modifies the molecular structure of the polymerizable compound by introducing specific chemical groups and adjusting molecular weight parameters. This allows achieving a lower melting point while maintaining the low molecular weight necessary for thin film formation, thus resolving the contradiction between reduced thickness and manageable melting point for industrial processing

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite polymerizable compound that combines multiple functional groups and structural elements. This composite structure enables simultaneous achievement of low melting point for ease of processing and appropriate molecular weight for thin film application, resolving the contradiction between film thickness reduction and processing temperature

Inventive Principle:
Principle #40Composite materials

2Length of stationary object

If existing low-molecular-weight polymerizable compounds are used, then thin films can be produced, but the production cost increases due to expensive reagents and multiple synthesis steps

Engineering Contradiction:
Improvefilm thicknessVSAvoidproduction cost
Core Design Contradiction:
Length of stationary objectVSEase of manufacture

Solution Approach 1:

The patent segments the synthesis process into fewer steps with simpler reactions, reducing the number of expensive reagents required. By simplifying the synthetic pathway while maintaining the ability to produce thin films, the production cost is reduced without compromising film thickness control

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs cheaper, more readily available reagents and simplifies the synthesis procedure, replacing expensive multi-step processes with more economical alternatives. This approach reduces production cost while still enabling the formation of thin retardation films through the polymerizable compound

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Measurement precision

If conventional retardation films are used, then specific monochromatic light conversion is accurate, but uniform polarized light conversion over wide wavelength band cannot be achieved

Engineering Contradiction:
Improvemonochromatic light conversion accuracyVSAvoidwavelength band coverage
Core Design Contradiction:
Measurement precisionVSAdaptability or versatility

Solution Approach 1:

The patent modifies the optical parameters of the polymerizable compound, specifically the wavelength dispersion characteristics, by adjusting the molecular structure. This enables the material to achieve reverse wavelength dispersion, allowing uniform polarized light conversion across a wide wavelength band while maintaining adequate performance for specific wavelengths

Inventive Principle:
Principle #35Parameter changes

4Length of stationary object

If polymerizable compounds with narrow liquid crystallinity temperature range are used, then thin films can be formed, but the applicable temperature range for processing becomes very limited

Engineering Contradiction:
Improvefilm thicknessVSAvoidliquid crystallinity temperature range
Core Design Contradiction:
Length of stationary objectVSDuration of action of moving object

Solution Approach 1:

The patent adjusts the temperature parameters of the polymerizable compound by modifying its molecular structure. This expands the liquid crystallinity temperature range, providing a broader processing window for thin film formation while maintaining the ability to produce thin retardation films

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables the production of optical films with low reflected luminance and uniform polarized light conversion over a wide wavelength band, suitable for use in thin retardation films, reducing production costs and improving performance.

Implementation Method 1

A polymerizable compound represented by formula (I) and a polymerizable composition including an initiator are used to produce a polymer

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Implementation Method 2

an optical film that achieves uniform conversion of polarized light over a wide wavelength band

Methodology Applied
Scientific EffectOptical anisotropy: Anisotropy

Implementation Method 3

uniform conversion of polarized light

Methodology Applied
Scientific EffectPolarization: Polarisation

Data Source

PatentUS11091452B2Polymerizable compound, polymerizable composition, polymer, optically anisotropic body, and method for producing polymerizable compound
Publication Date: 2021.08.17 ZEON CORP
  • US11091452B2 patent drawing
  • US11091452B2 patent drawing
  • US11091452B2 patent drawing

AI summary

A polymerizable compound has a practical low melting point, excellent solubility in a general-purpose solvent, and can produce an optical film at low cost, exhibits low reflected luminance, and achieves uniform conversion of polarized light over a wide wavelength band, an optically anisotropic article.