Polymerization Effluent Separation via Flash Vaporization

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Solution Overview

Problem

Conventional methods for recycling feedstock components from polymerization reaction effluents are costly and inefficient, requiring extensive equipment and energy, and lack sufficient control parameters to prevent process delays and inefficiencies.

Innovation Solution

A system comprising a polymerization reactor, flash-line heater, flash chamber, first and second columns, and accumulators is used to separate and recycle components from the effluent stream, optimizing the separation process by minimizing equipment and energy consumption and enhancing control parameters.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional purification processes with multiple distillation columns, compressors, and refrigeration units are used, then high purity feedstock components are achieved, but equipment costs and energy consumption increase significantly

Engineering Contradiction:
Improvefeedstock purityVSAvoidenergy consumption
Core Design Contradiction:
Manufacturing precisionVSUse of energy by stationary object

Solution Approach 1:

The patent extracts and removes unnecessary equipment (compressors, refrigeration units, multiple distillation columns) from the conventional purification process, retaining only the essential flash chamber and single distillation column while achieving the same purification effect through optimized process parameters

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes operating parameters including temperature, pressure, and flow rate conditions to optimize the flash vaporization and distillation processes, enabling high purity separation with reduced energy input and simplified equipment

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If conventional purification processes with numerous distillation columns and equipment are used, then high purity feedstock components are achieved, but device complexity increases

Engineering Contradiction:
Improvefeedstock purityVSAvoidequipment complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent removes redundant equipment including multiple distillation columns, compressors, and refrigeration units, retaining only the essential flash chamber and single distillation column while achieving the same purification effect

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent combines multiple separation functions into a simplified integrated system where the flash chamber performs initial separation and the single distillation column completes purification, replacing the conventional multi-column arrangement

Inventive Principle:
Principle #5Merging (Combining)

3Quantity of substance

If conventional purification processes are used, then feedstock components are recovered, but process time increases leading to delays and inefficiencies

Engineering Contradiction:
Improvefeedstock recoveryVSAvoidprocess time
Core Design Contradiction:
Quantity of substanceVSLoss of time

Solution Approach 1:

The patent uses flash vaporization to rapidly separate components in a single stage process, skipping the multiple sequential distillation steps required in conventional processes and significantly reducing processing time

Inventive Principle:
Principle #21Skipping (Rushing through)

Solution Approach 2:

The patent performs preliminary separation in the flash chamber before the distillation column, pre-concentrating the feedstock components and reducing the burden on subsequent purification steps to accelerate overall processing

Inventive Principle:
Principle #10Preliminary action

4Quantity of substance

If conventional purification processes are used, then feedstock components are recovered, but equipment and energy costs represent a significant proportion of total production cost

Engineering Contradiction:
Improvefeedstock recoveryVSAvoidproduction cost
Core Design Contradiction:
Quantity of substanceVSUse of energy by stationary object

Solution Approach 1:

The patent removes expensive equipment including compressors, refrigeration units, and multiple distillation columns from the process, retaining only essential components while achieving the same feedstock recovery objective

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent optimizes operating parameters to reduce energy consumption in the flash vaporization and distillation processes, directly lowering the energy cost component of total production cost

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively recycles reusable components, reduces costs and process complexity, and improves control over the recycling process, leading to increased efficiency and reduced downtime.

Implementation Method 1

heating the effluent stream

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 2

separating the heated effluent stream into a polymer product stream and a flash gas stream

Methodology Applied
Scientific EffectFlash vaporization: Flash Evaporation

Implementation Method 3

routing the flash gas stream to a first fractionation column... routing a second stream to a second fractionation column

Methodology Applied
Scientific EffectFractional distillation: Distillation

Data Source

PatentEP3133089B1System and method for processing reactor polymerization effluent
Publication Date: 2018.01.17 CHEVRON PHILLIPS CHEMICAL COMPANY LP
  • EP3133089B1 patent drawingFigure 1
  • EP3133089B1 patent drawingFigure 2
  • EP3133089B1 patent drawingFigure 3

AI summary

A method of treating a polymerization reactor effluent stream comprising: recovering the effluent stream from the polymerization reactor, flashing the effluent stream to form a flash gas stream, feeding the flash gas stream into a first column, recovering a first overhead stream, a first bottom stream, and a side stream, from the first column, wherein the side stream substantially comprises hexane, feeding the first overhead stream into an accumulator vessel, recovering a second overhead stream and a second bottom stream from the accumulator vessel, wherein the second bottom stream substantially comprises isobutane, feeding the second overhead stream to a second column, and recovering a third overhead stream and a third bottom stream from the second column, wherein the third bottom stream is substantially olefin-free.