Gas Phase Polymerization Reactor Temperature Control

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Solution Overview

Problem

Existing methods for producing water-absorbing polymer particles are prone to failures and do not consistently produce high-quality products, particularly in the polymerization of drops in a gas phase surrounding the drops, where temperature control is inadequate.

Innovation Solution

A process where drops containing monomers are polymerized in a heated gas phase, with the gas flowing through the reactor, and the temperature of the gas leaving the reactor is regulated by controlling the heating power using heat exchangers, ensuring continuous comparison and adjustment of the gas outlet temperature to maintain optimal conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If temperature control is not implemented in the gas phase polymerization process, then the process is simpler to operate, but the product quality becomes inconsistent and the process becomes prone to failures

Engineering Contradiction:
Improveprocess reliabilityVSAvoidtemperature control system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent implements a temperature control system that continuously measures the gas outlet temperature from the polymerization reactor and uses this feedback signal to adjust the heating power. This closed-loop feedback mechanism ensures consistent product quality by maintaining optimal polymerization conditions while preventing process failures, resolving the contradiction between reliability and system complexity.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent controls the polymerization process by dynamically adjusting the heating power parameter based on the measured gas outlet temperature. By changing this critical parameter in response to process conditions, the system maintains reliable and consistent product quality without requiring overly complex control architecture.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If the heating power is increased to maintain gas outlet temperature, then the polymerization efficiency improves, but the energy consumption increases

Engineering Contradiction:
Improvepolymerization efficiencyVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The feedback control system monitors the gas outlet temperature and adjusts heating power only to the extent necessary to maintain optimal polymerization conditions. This prevents excessive energy consumption while ensuring sufficient polymerization efficiency, as the heating power is dynamically optimized rather than continuously maximized.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The heating power is made dynamic rather than static, adjusting in real-time according to process conditions. This dynamic adaptation allows the system to maintain high polymerization efficiency when needed while reducing energy consumption during periods when less heating is required, resolving the contradiction between productivity and energy use.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process results in the production of water-absorbing polymer particles of consistent quality, with improved centrifuge retention capacity, reduced extractable content, and controlled particle size, enhancing the reliability and efficiency of the production process.

Implementation Method 1

the gas flowing through the reactor is preheated accordingly using suitable heat exchangers before entering the reactor

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 2

the monomers are polymerized in a heated gas phase surrounding the drops

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentEP2089151B1Regulation of a process for producing water-absorbing polymer particles in a heated gas phase
Publication Date: 2016.05.25 BASF SE
  • EP2089151B1 patent drawing

AI summary

A process for producing water-absorbing polymer particles, wherein droplets comprising monomers are generated, the monomers are polymerized in a heated gas phase surrounding the droplets, the gas flows through the polymerization reactor and the temperature of the gas leaving the polymerization reactor is regulated.