Polyol Carrier Fluids for Fuel Additives

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Solution Overview

Problem

Current fuel performance additives, despite incorporating detergents and carriers, face limitations in effectively controlling intake valve deposits and injector deposits in spark-ignition internal combustion engines, with carrier fluids lacking detergent activity and contributing to combustion chamber deposits.

Innovation Solution

A fuel additive composition comprising a Mannich detergent reaction product combined with a blend of aliphatic C16 to C18 alkoxylated alcohols as a carrier fluid, which exhibits unexpected performance improvements in reducing intake valve sticking and deposits, while also allowing for reduced hydrocarbon solvent usage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If conventional carrier fluids (petroleum-based or synthetic) are used to disperse detergents, then detergent dispersal and fluidizing properties are improved, but detergent activity and deposit control are worsened

Engineering Contradiction:
Improvedetergent dispersalVSAvoiddeposit control
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The polyol carrier fluid performs multiple functions simultaneously: it acts as a dispersant for the detergent, provides fluidizing properties to the fuel, and contributes direct detergent activity for deposit control. This multi-functionality resolves the contradiction by eliminating the need for separate carrier and detergent components.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The invention uses a composite carrier fluid system where polyols are combined with specific additives to create a carrier that has both dispersal properties and detergent activity. This composite approach allows the carrier to provide both ease of operation and harmful factor control.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If mineral oils are used as carrier fluids, then fluidizing properties are improved, but combustion chamber deposits are worsened

Engineering Contradiction:
Improvefluidizing propertyVSAvoidcombustion chamber deposits
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The invention extracts and eliminates mineral oil components from the carrier fluid system, replacing them with polyols that provide equivalent fluidizing properties without the harmful combustion chamber deposit formation. This extraction of the harmful component resolves the contradiction.

Inventive Principle:
Principle #2Taking out (Extraction)

3Object-generated harmful factors

If carrier fluids with high detergent activity are used, then deposit control is improved, but fuel economy and engine wear are worsened

Engineering Contradiction:
Improvedeposit controlVSAvoidfuel economy
Core Design Contradiction:
Object-generated harmful factorsVSLoss of energy

Solution Approach 1:

The invention changes the chemical parameters of the carrier fluid by using polyols with specific molecular weights and structures that provide optimal balance between detergent activity and fuel economy. By adjusting these parameters, the system achieves effective deposit control without excessive energy loss.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP3375848B1Polyol carrier fluids and fuel compositions including polyol carrier fluids
Publication Date: 2022.01.12 AFTON CHEMICAL CORPORATION
  • EP3375848B1 patent drawingFigure 1~2
  • EP3375848B1 patent drawingFigure 3~4
  • EP3375848B1 patent drawingFigure 5~6

AI summary

A carrier fluid or fluidizer for use in fuel performance additives or fuels including such additives is described herein. The novel carrier fluids include a unique blend of alkoxylated alcohols or polyols providing unexpected performance improvements to fuel performance additives and fuels incorporating the additives. The carrier fluids, when combined with at least a detergent, provide desired valve stick performance and unexpectedly improve the intake valve deposit performance at the same time.