Liquid Dispersion Using Polyol and Surfactant for Cosmetic Stability

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Solution Overview

Problem

Dispersing inorganic powder in a dispersion medium is costly and requires high expertise, and large particle-sized inorganic powders tend to settle, leading to poor dispersion stability and phase separation in liquid dispersions, making them unsuitable for both O/W and W/O cosmetic products.

Innovation Solution

A liquid dispersion containing a polyol, a nonionic surfactant, and a hydrophobized inorganic powder with low water content (1% or less) and a hydrophobized inorganic powder of 150 nm to 700 nm particle size, which maintains stability and prevents caking and phase separation, allowing for use in both O/W and W/O cosmetic products.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If inorganic powder is dispersed in a dispersion medium to facilitate good color development, then color performance is improved, but dispersing requires adequate facility and manpower, increasing cost and complexity

Engineering Contradiction:
Improvecolor developmentVSAvoiddispersing facility and manpower
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The inorganic powder is pre-dispersed in a polyol-based liquid medium during manufacturing, creating a ready-to-use liquid dispersion that eliminates the need for separate dispersing facilities and manpower at the application site. The powder is thoroughly mixed with polyol and nonionic surfactant before supply, so no additional dispersing equipment is needed when applying to cosmetic products.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

A polyol-based liquid medium serves as an intermediary carrier between the inorganic powder and the final cosmetic product. This liquid medium pre-disperses the powder particles and transports them directly to the application, replacing complex dispersing facilities with a simple liquid delivery system.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Quantity of substance

If inorganic powder with large particle size (150 nm or more) is used in liquid dispersion, then pigment grade performance is achieved, but the inorganic powder easily settles, leading to poor dispersion stability and phase separation

Engineering Contradiction:
Improveparticle size for pigment gradeVSAvoiddispersion stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent changes the liquid medium parameters from water-based to polyol-based (using compounds like ethylene glycol, propylene glycol, or glycerol). This parameter change in the dispersion medium prevents settling of large particle-sized inorganic powder by providing better wetting and suspension properties, achieving both pigment grade particle size and long-term dispersion stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Nonionic surfactants act as intermediaries between the inorganic powder particles and the polyol medium. These surfactants adsorb onto the particle surfaces, providing steric stabilization that prevents aggregation and settling, thereby maintaining dispersion stability of large particle-sized pigment grade inorganic powder.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Adaptability or versatility

If water is used as the dispersion medium for inorganic powder, then the dispersion can be applied to O/W type cosmetic products, but the inorganic powder settles and caking occurs over time

Engineering Contradiction:
Improveapplicability to O/W cosmetic productsVSAvoidlong-term dispersion stability
Core Design Contradiction:
Adaptability or versatilityVSStability of the object's composition

Solution Approach 1:

The patent changes the dispersion medium from water to polyol compounds. This parameter change fundamentally alters the interaction between the medium and inorganic powder particles, preventing the settling and caking that occur in aqueous systems while maintaining adaptability to cosmetic formulations through the hydrophilic nature of polyols.

Inventive Principle:
Principle #35Parameter changes

4Shape

If organically surface-treated fine particle inorganic powder is dispersed in water, then fine texture and good handling properties are achieved, but the inorganic powder does not provide adequate stability for pigment grade particle sizes

Engineering Contradiction:
Improvefine texture and handling propertiesVSAvoidstability of liquid dispersion
Core Design Contradiction:
ShapeVSStability of the object's composition

Solution Approach 1:

The patent changes both the particle size parameter and the dispersion medium parameter simultaneously. By using polyol instead of water and combining it with appropriate nonionic surfactants, the system achieves stable dispersion of larger pigment-grade particles while maintaining the fine texture and handling properties associated with surface-treated inorganic powders.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The liquid dispersion achieves long-term stability, reducing costs and simplifying the dispersing process, while providing good color development, texture, and water and sweat repellency in cosmetic products.

Implementation Method 1

a liquid dispersion containing a polyol, a nonionic surfactant, and a hydrophobized inorganic powder

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

a hydrophobized inorganic powder (C), wherein the water content in 100% by mass of the liquid dispersion is 1% by mass or less

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Data Source

PatentUS11033468B2Liquid dispersion and uses thereof
Publication Date: 2021.06.15 SAKAI CHEM IND CO LTD

AI summary

The present invention provides a liquid dispersion capable of stably maintaining the dispersed state for a long time and suitably applicable to both O/W type cosmetic products and W/O type cosmetic products. The present invention also provides a cosmetic raw material containing the liquid dispersion and a cosmetic product containing the liquid dispersion. The present invention provides a liquid dispersion containing a polyol (A); a nonionic surfactant (B); and a hydrophobized inorganic powder (C), wherein the water content in 100% by mass of the liquid dispersion is 1% by mass or less.