Polyol ester compositions

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Solution Overview

Problem

Current methods for recharging lubricants into low GWP HFO-1234yf automotive air conditioning (A/C) systems are inefficient, requiring manual injection and prone to lubricant adhesion in hoses, leading to incomplete delivery and increased complexity in both vehicle and stationary A/C systems.

Innovation Solution

A composition comprising 50-80 wt% polyol ester (POE) lubricant and 20-50 wt% low GWP refrigerant, co-packaged to ensure miscibility, allowing the refrigerant to atomize and convey the lubricant/additive mixture into the A/C system, reducing adhesion and improving delivery efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If manual injection method is used to recharge lubricant into A/C system, then the process can be performed with simple equipment, but the lubricant delivery is incomplete and adhesion to hoses occurs

Engineering Contradiction:
Improvesimplicity of recharging equipmentVSAvoidlubricant delivery efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent uses refrigerant as an intermediary carrier to transport lubricant from the charging can to the A/C system. The refrigerant forms a miscible mixture with the lubricant and delivers it through the hose without adhesion, solving the incomplete delivery problem while using simple manual injection equipment

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the physical state and composition parameters by mixing lubricant with refrigerant to create a miscible mixture. This parameter change allows the lubricant to be conveyed as a fluid mixture rather than pure lubricant, preventing adhesion to hose walls and enabling complete delivery

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If pure lubricant is injected into A/C system, then the lubricant can be delivered directly, but adhesion to hose walls occurs and delivery is incomplete

Engineering Contradiction:
Improveamount of lubricant deliveredVSAvoidease of lubricant injection
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

Refrigerant serves as a carrier medium that miscibly mixes with lubricant, enabling complete transfer through the hose without adhesion. This intermediary approach ensures full quantity delivery while simplifying the injection operation to a single canned charge

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the delivery parameter from pure lubricant injection to refrigerant-lubricant mixture injection. This parameter change eliminates adhesion losses and ensures complete quantity transfer while simplifying the operation

Inventive Principle:
Principle #35Parameter changes

3Productivity

If refrigerant is used to convey lubricant, then delivery efficiency is improved and adhesion is reduced, but the composition must maintain miscibility across temperature and pressure ranges

Engineering Contradiction:
Improvelubricant delivery efficiencyVSAvoidmiscibility stability of refrigerant-lubricant mixture
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent selects specific refrigerant and lubricant combinations with proven miscibility across the A/C operating temperature and pressure range. By controlling the composition parameters and selecting compatible materials, the mixture maintains stability throughout the delivery and operation cycles

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Ensures more effective and convenient lubricant introduction into A/C systems, maintaining miscibility across a wide temperature range and pressure conditions, enhancing system performance and reducing manual handling complexities.

Implementation Method 1

the refrigerant will change state from compressed liquefied gas to refrigerant gas. During this process, refrigerant which is miscible with the lubricant will atomize the lubricant or lubricant/additive mixture and will convey the lubricant or lubricant/additive mixture further along the hose and into the A/C system

Methodology Applied
Scientific EffectAtomization:

Implementation Method 2

In the hand injector or hand pump, lubricant flow is controlled by the lubricant viscosity and suction of the A/C compressor

Methodology Applied
Scientific EffectSuction: Suction

Data Source

PatentUS10913913B2Polyol ester compositions
Publication Date: 2021.02.09 THE CHEMOURS CO FC LLC
  • US10913913B2 patent drawing
  • US10913913B2 patent drawing
  • US10913913B2 patent drawing

AI summary

Compositions, systems and methods for introducing lubricants, and additives, that are designed to work with environmentally friendly refrigerants into vehicle heat management systems including passenger compartment air conditioning (A/C) systems are disclosed. Methods for charging lubricants and specific additives using environmentally desirable (low GWP) refrigerant or refrigerant blend compositions into an environmentally friendly system, such as a system that uses HFO-1234yf, are also disclosed.