Polyol Ester Lubricant Composition for Hydrogen-Fueled Engine Pre-Ignition

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Solution Overview

Problem

Hydrogen-fueled internal combustion engines exhibit a higher pre-ignition tendency due to their increased reactivity, leading to reduced engine efficiency and the need to operate at lower pressures, which conventional lubricants fail to address effectively.

Innovation Solution

A lubricant composition comprising 30.0 to 99.8 mass % of a polyol ester oil base stock and 1.0 to 30.0 mass % polyisobutylene, with low ash, low sulfur, and low phosphorus content, designed to reduce pre-ignition frequency in hydrogen-fueled engines.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional lubricants are used in hydrogen-fueled engines, then the engine can operate with standard lubrication, but the pre-ignition tendency increases due to higher reactivity of hydrogen fuel

Engineering Contradiction:
Improvecompatibility with hydrogen fuelVSAvoidpre-ignition tendency
Core Design Contradiction:
Adaptability or versatilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the lubricant by using polyol ester base stocks with specific viscosity grades (0W-20, 5W-20, 5W-30, 10W-30) and incorporating specific additive packages. This parameter change in lubricant composition reduces the pre-ignition tendency caused by hydrogen fuel's high reactivity, allowing the engine to maintain compatibility with hydrogen while mitigating the harmful pre-ignition effect.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If the engine operates at lower pressures to avoid pre-ignition, then pre-ignition tendency is reduced, but engine efficiency decreases

Engineering Contradiction:
Improvepre-ignition tendencyVSAvoidengine efficiency
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent introduces a specially formulated lubricant composition as an intermediary substance between the hydrogen fuel and the engine components. This lubricant with polyol ester base stock and specific additives acts as a mediator that reduces pre-ignition tendency, thereby enabling the engine to operate at higher pressures and maintain efficiency while using hydrogen fuel, without directly modifying the fuel or engine structure.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Stability of the object's composition

If polyisobutylene is added to the lubricant composition, then viscosity stability improves, but the complexity of the lubricant formulation increases

Engineering Contradiction:
Improveviscosity stabilityVSAvoidlubricant formulation complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent creates a composite lubricant formulation by combining polyol ester base stocks with polyisobutylene additives in specific concentrations. This composite approach provides improved viscosity stability and performance characteristics that neither component could achieve alone, accepting the increased formulation complexity as necessary to obtain the enhanced stability and performance benefits required for hydrogen-fueled engine operation.

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS12384980B2Internal combustion engine lubricant
Publication Date: 2025.08.12 EXXONMOBIL TECHNOLOGY & ENGINEERING CO
  • US12384980B2 patent drawing
  • US12384980B2 patent drawing
  • US12384980B2 patent drawing

AI summary

A lubricant composition may be of use in lubrication of an internal combustion engine. A method of utilizing such a lubricant composition may include: lubricating an internal combustion engine using a lubricant composition comprising: from about 30.0 mass % to about 99.8 mass % of an oil base stock, based on a total mass of the lubricant composition, the oil base stock comprising at least one polyol ester; and from 1.0 mass % to 30.0 mass % polyisobutylene, based on a total mass of the lubricant composition; and combusting a fuel in the internal combustion engine.