Polyolefin Adhesive Composition for Extended Open Time

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Solution Overview

Problem

Current adhesive compositions, particularly hot melt adhesives, face challenges in maintaining bonding performance at lower temperatures and have limited open time, making them less suitable for high-line-speed applications.

Innovation Solution

An adhesive composition comprising an olefin block copolymer with specific hard and soft block distributions, a tackifier, and an oil, which provides improved open time and bonding performance even at lower temperatures (100-120°C) by optimizing the molecular weight, crystallinity, and viscosity profile.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If hot melt adhesive is applied at lower temperatures (100-120°C), then energy consumption is reduced and substrate damage is minimized, but open time is shortened and bonding performance deteriorates

Engineering Contradiction:
Improveapplication temperatureVSAvoidopen time
Core Design Contradiction:
TemperatureVSDuration of action of moving object

Solution Approach 1:

The patent modifies the chemical composition parameters of the adhesive by incorporating specific polyolefin copolymers with controlled comonomer content (3-15 mol%) and molecular weight (10,000-100,000 g/mol), along with tackifiers and oils in optimized ratios, to achieve lower melting points and extended open times at reduced application temperatures

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite adhesive system combining polyolefin copolymer base resin, tackifiers (rosin, terpene, or phenolic resins), and plasticizing oils to achieve synergistic effects that extend open time and maintain bonding performance at lower temperatures than conventional hot melt adhesives

Inventive Principle:
Principle #40Composite materials

2Productivity

If machine line speed is increased, then productivity is improved, but adhesive open time becomes insufficient for proper bonding

Engineering Contradiction:
Improveline speedVSAvoidopen time
Core Design Contradiction:
ProductivityVSDuration of action of moving object

Solution Approach 1:

The patent adjusts the rheological parameters of the adhesive by selecting copolymers with specific molecular weights (10,000-100,000 g/mol) and comonomer contents (3-15 mol%), and optimizing the ratio of tackifier to base polymer, to achieve extended open times that match high-speed production requirements

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent formulates the adhesive to exhibit dynamic viscoelastic properties that maintain adequate open time at rest but allow rapid setting under pressure, enabling synchronization with high-speed machinery cycles

Inventive Principle:
Principle #15Dynamics

3Strength

If conventional polymer-based hot melt adhesive is used, then adhesive strength is achieved, but open time is limited and high-line-speed applications are difficult

Engineering Contradiction:
Improveadhesive strengthVSAvoidopen time
Core Design Contradiction:
StrengthVSDuration of action of moving object

Solution Approach 1:

The patent develops a composite formulation combining polyolefin copolymers with controlled comonomer content (3-15 mol%), tackifiers (5-20 wt%), and plasticizing oils (5-20 wt%) to achieve both high adhesive strength and extended open time, overcoming the limitations of conventional single-polymer hot melt adhesives

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves extended open time and enhanced bonding performance at lower temperatures, suitable for high-line-speed applications, with improved wetting and adhesion properties in nonwoven applications.

Implementation Method 1

Hot-melt adhesives at ambient temperature are generally solid materials that can be heated to a melt to hold adherents or substrates together upon cooling and solidifying

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 2

An adhesive is a substance capable of holding solid materials (e.g., adherents or substrates) together by surface attachment

Methodology Applied
Scientific EffectWetting: Wetting

Data Source

PatentEP2831190B1Polyolefin adhesive composition
Publication Date: 2016.12.14 DOW GLOBAL TECHNOLOGIES LLC
  • EP2831190B1 patent drawingFigure 1
  • EP2831190B1 patent drawingFigure 2
  • EP2831190B1 patent drawingFigure 3

AI summary

The invention provides an adhesive formulation comprising an olefin block copolymer comprising hard blocks and soft blocks wherein the hard blocks comprise 4-8 mol% comonomer; and are present in an amount of 20 wt% - 45 wt%. This formulation is particularly advantageous for use in hot melt adhesives but may be used in other applications as well.