Polyolefin-Plastic Welding Primer for Dissimilar Bonding

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Solution Overview

Problem

Existing methods fail to achieve a strong, stable, and durable connection between different types of plastics, such as polypropylene and polycarbonate or polypropylene and ABS, when attempting to weld them directly, resulting in low mechanical strength and instability under various conditions.

Innovation Solution

A method involving the use of a primer containing maleic anhydride-grafted polyolefin polymer and polyester, which is applied to the surfaces of the plastics to be welded, facilitating a stable and permanent bond by making the plastics compatible during the welding process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If direct welding is attempted between dissimilar plastics (e.g., polypropylene and polycarbonate), then the welding process is simple and fast, but the mechanical strength of the bond is very low or non-existent

Engineering Contradiction:
Improvewelding speedVSAvoidbond strength
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

A primer layer comprising maleic anhydride-grafted polyolefin polymer and polyester is applied to at least one of the surfaces to be joined. This primer acts as an intermediary between the polyolefin plastic and the second plastic, enabling chemical bonding to both substrates. The maleic anhydride groups react with hydroxyl groups on the second plastic surface, while the polyester component provides compatibility with polyolefin, thus resolving the incompatibility issue and achieving strong bonds between dissimilar plastics without compromising welding efficiency

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The primer is formulated as a composite material combining maleic anhydride-grafted polyolefin polymer (typically 70-95 wt%) and polyester (typically 5-30 wt%). This composite structure leverages the polyolefin component's affinity for polyolefin substrates and the polyester component's ability to bond with polar plastics through hydroxyl group reactions, creating a dual-functional adhesive layer that enables welding of dissimilar plastics with high mechanical strength

Inventive Principle:
Principle #40Composite materials

2Strength

If adhesive bonding is used to join different plastics, then a strong bond can be achieved, but the bonding process is time-consuming and requires extensive pretreatment

Engineering Contradiction:
Improvebond strengthVSAvoidbonding time
Core Design Contradiction:
StrengthVSLoss of time

Solution Approach 1:

The invention replaces traditional adhesive bonding (a chemical process requiring pretreatment and long curing times) with a welding process enhanced by a primer layer. The primer enables direct thermal or ultrasonic welding of dissimilar plastics, substituting the lengthy adhesive bonding process with a faster welding operation. The primer's chemical bonding capability allows the welding process to achieve adhesive-strength bonds without the time-consuming pretreatment and curing steps

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The primer layer is applied in advance to the surface(s) to be welded, performing preliminary chemical preparation. This preliminary action creates reactive sites (through maleic anhydride groups) and ensures surface compatibility before the welding process begins. As a result, the actual welding step can proceed quickly without requiring extensive pretreatment during the bonding process itself, significantly reducing total processing time while maintaining strong bond strength

Inventive Principle:
Principle #10Preliminary action

3Reliability

If mechanical fastening is used to join plastics, then the connection is stable, but the application process is complicated and requires additional fasteners

Engineering Contradiction:
Improveconnection stabilityVSAvoidjoining process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The primer layer serves as a chemical intermediary that enables direct material bonding between plastics, eliminating the need for mechanical fasteners. By creating a chemically active surface layer that bonds to both substrates, the primer allows for simple welding operations to achieve stable connections, thereby reducing device complexity while maintaining connection reliability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the fundamental bonding mechanism from mechanical (physical interlocking with fasteners) to chemical (covalent bonding through maleic anhydride groups and polyester). This parameter change in the bonding approach allows for simpler joining processes without compromising connection stability, as the chemical bonds formed are inherently strong and permanent

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The primer enables the achievement of tensile strengths greater than 2 MPa, with some combinations reaching up to 16.89 N/mm², providing a strong and durable connection between otherwise incompatible plastics.

Implementation Method 1

the primer contains at least one polymer containing maleic anhydride, in particular at least one maleic anhydride-grafted polyolefin polymer, and at least one polyester... particularly stable, materially bonded connections between the plastics could be obtained

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Data Source

PatentEP3315290B1Method of welding a polyolefin plastic with another plastic
Publication Date: 2020.02.26 HENKEL KGAA
  • EP3315290B1 patent drawing

AI summary

A method for welding a polyolefin plastic to a second plastic using a primer, wherein the primer comprises at least one maleic anhydride-containing polymer and at least one polyester. The second plastic is selected from the group consisting of polycarbonate (PC), acrylonitrile butadiene styrene (ABS), polymethyl methacrylate (PMMA), polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polystyrene (PS), polystyrene acrylonitrile (SAN), polyacrylonitrile styrene acrylate (ASA), methyl methacrylate acrylonitrile butadiene styrene (MABS), high-impact polystyrene (HIPS), and polyamide (PA). The present invention further relates to products welded accordingly.