Hydroxyalkyl Polyoxylene Glycol Ether Adjuvant for Pesticide Uptake

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current agrochemical formulations often require high concentrations of active ingredients and struggle with compatibility issues and limited effectiveness under adverse conditions, particularly in treating phytopathogenic fungi and undesirable plant growth.

Innovation Solution

A composition comprising a pesticide and hydroxyalkyl polyoxylene glycol ether, which acts as an adjuvant to enhance the activity and uptake of pesticides, reducing the required active ingredient concentration while improving compatibility and effectiveness under adverse conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high concentrations of active ingredients are used in agrochemical formulations, then effectiveness against phytopathogenic fungi and undesirable plant growth is improved, but cost increases and compatibility issues arise

Engineering Contradiction:
ImproveeffectivenessVSAvoidactive ingredient concentration
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent introduces hydroxyalkyl polyoxylene glycol ethers as intermediary substances (adjuvants) that mediate between the active ingredient and the target organism. These compounds enhance the biological activity and effectiveness of the active ingredient, allowing lower concentrations to achieve the same or better efficacy. The adjuvants act as carriers or penetration enhancers, facilitating better delivery and action of the active ingredient.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the formulation parameters by incorporating specific adjuvants (hydroxyalkyl polyoxylene glycol ethers) that modify the physical and chemical properties of the formulation. This changes the delivery mechanism and bioavailability of the active ingredient, enabling effective pest control at reduced concentrations.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional adjuvants are used to improve pesticide activity, then effectiveness is enhanced, but compatibility issues and limited effectiveness under adverse conditions persist

Engineering Contradiction:
ImproveeffectivenessVSAvoidcompatibility and effectiveness under adverse conditions
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent creates composite formulations by combining pesticides with hydroxyalkyl polyoxylene glycol ethers. This composite approach integrates multiple functional components that work synergistically: the active ingredient provides pesticidal activity while the adjuvant provides enhanced compatibility, stability, and performance under adverse environmental conditions.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The hydroxyalkyl polyoxylene glycol ethers serve multiple functions simultaneously: they act as penetration enhancers, compatibility agents, stability improvers, and effectiveness boosters. This multi-functionality allows a single adjuvant component to address multiple formulation challenges and improve performance across diverse application conditions.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Quantity of substance

If reduced amounts of active ingredient are used, then cost is minimized and legislation requirements are met, but effectiveness may be compromised

Engineering Contradiction:
Improveactive ingredient concentrationVSAvoideffectiveness
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The adjuvant acts as an intermediary that amplifies the effect of reduced active ingredient concentrations. By incorporating hydroxyalkyl polyoxylene glycol ethers, the formulation compensates for lower active ingredient levels through enhanced penetration, retention, and biological activity, maintaining effectiveness while reducing quantity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The hydroxyalkyl polyoxylene glycol ether enhances the activity and uptake of pesticides, allowing for reduced active ingredient usage, improved compatibility, and increased effectiveness against phytopathogenic fungi and undesirable plant growth, as demonstrated by field trials and greenhouse studies.

Implementation Method 1

Frequently, they take the form of surface-active or salt-like compounds. As regards the uptake of the active ingredient into the leaf, surface-active substances may act as modifiers and adjuvants.

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

In general, it is assumed that suitable surface-active substances are capable of increasing the effective contact area of fluids on leaves by providing better wetting.

Methodology Applied
Scientific EffectWetting: Wetting

Implementation Method 3

Moreover, certain surface-active substances act as plasticizer, i.e. are capable of changing the epicuticular waxy layer from a crystalline to an amorphous state, which facilitates the sorption of the active ingredient.

Methodology Applied
Scientific EffectPlasticizer:

Implementation Method 4

Furthermore, some surface-active substances are also capable of improving the solubility of active ingredients in formulations, thereby avoiding, or at least delaying, crystal formation.

Methodology Applied
Scientific EffectSolubility enhancement: Solvation

Implementation Method 5

Finally, in certain cases they can also influence the absorption of active ingredients by retaining moisture.

Methodology Applied
Scientific EffectMoisture retention: Absorption (physical)

Data Source

PatentEP3139740B1Composition comprising a pesticide and a hydroxyalkyl polyoxylene glycol ether
Publication Date: 2020.09.16 BASF SE
  • EP3139740B1 patent drawing
  • EP3139740B1 patent drawing
  • EP3139740B1 patent drawing

AI summary

The present invention relates to a composition comprising a pesticide and hydroxyalkyl polyoxylene glycol ether of the formula (I). The invention further relates to use of hydroxyalkyl polyoxylene glycol ether as adjuvants in pesticide-comprising spray mixtures. The invention further relates to a method for controlling phytopathogenic fungi and/or undesirable plant growth and/or undesirable insect or mite infestation and/or for regulating the growth of plants, wherein the composition is allowed to act on the respective pests, the habitat thereof or the plants to be protected from the respective pest, on the soil and/or on undesirable plants and/or the crop plants and/or the habitat thereof. Furthermore, the invention relates to seed comprising the composition. The present invention comprises combinations of preferred features with other preferred features.