Polyphenol Adhesive Film for Hydrogel-to-Rigid Bonding

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Solution Overview

Problem

Existing soft electronic devices face challenges in integrating soft and rigid components due to differences in chemical and mechanical properties, particularly the difficulty in achieving stable adhesion between hydrogels and other materials.

Innovation Solution

An adhesive film comprising a first adhesive layer with a polyphenol-based compound and a composite layer with alternating resin and second adhesive layers, utilizing hydrogen bonding and galloyl interaction, is used to create an adhesive member that can bond with various substrates, including soft and rigid materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If hydrogels are used as soft components in soft electronic devices, then flexibility and biocompatibility are improved, but adhesion to rigid components deteriorates due to high water content

Engineering Contradiction:
Improveflexibility and biocompatibilityVSAvoidadhesion strength
Core Design Contradiction:
Adaptability or versatilityVSStrength

Solution Approach 1:

The patent introduces a polyphenol-based adhesive layer as an intermediary between hydrogel soft components and rigid components. This adhesive layer contains polyphenol compounds that can form strong hydrogen bonds and galloyl interactions with both hydrophilic polymers in hydrogels and surfaces of rigid materials, thereby mediating the adhesion interface and resolving the contradiction between maintaining hydrogel flexibility and achieving strong bonding.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite adhesive structure combining polyphenol-based compounds with hydrophilic polymer matrices. This composite material leverages the hydrophilic nature of polymers to interact with hydrogels while polyphenol moieties provide strong adhesion to rigid substrates through multiple bonding mechanisms, thus achieving both flexibility compatibility and strong adhesion.

Inventive Principle:
Principle #40Composite materials

2Productivity

If rigid components are integrated into soft electronic devices, then data processing capability is improved, but stable integration deteriorates due to differences in chemical and mechanical properties

Engineering Contradiction:
Improvedata processing capabilityVSAvoidintegration stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The polyphenol-based adhesive layer serves as a mediator between rigid components (IC chips, PCBs) and soft components. The adhesive's ability to form strong interactions with both hydrophilic surfaces and rigid material surfaces creates a stable interface that bridges the chemical and mechanical property differences, enabling reliable integration of rigid components into soft devices.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The adhesive composition utilizes parameter changes in bonding mechanisms by employing multiple interaction types (hydrogen bonding, galloyl interactions, pi-pi stacking) that can adapt to different substrate properties. This multi-mechanism approach allows the adhesive to maintain stable bonding across diverse material interfaces despite differences in chemical and mechanical parameters.

Inventive Principle:
Principle #35Parameter changes

3Strength

If polyphenol-based adhesive layers are formed, then adhesive strength is improved through hydrogen bonding and galloyl interaction, but manufacturing complexity increases due to multi-layer composite structure

Engineering Contradiction:
Improveadhesive strengthVSAvoidmanufacturing complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The adhesive film is segmented into multiple functional layers: a polyphenol-based adhesive layer for strong bonding, and a hydrophilic polymer resin layer for compatibility with soft components. This segmentation allows each layer to perform its specific function optimally while the overall structure remains manufacturable through sequential coating processes.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The polyphenol-based adhesive layer is designed to provide multiple bonding mechanisms (hydrogen bonding, galloyl interactions) simultaneously, making it universally applicable to various substrate types. This multi-functionality reduces the need for different adhesives for different materials, simplifying the overall manufacturing process despite the multi-layer structure.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The adhesive film provides strong mechanical strength, adhesive strength, flexibility, and biocompatibility, enabling robust bonding between different materials and maintaining high transparency, which is essential for stable operation of soft electronic devices under dynamic conditions.

Implementation Method 1

excellent mechanical strength and adhesive strength due to hydrogen bonding and galloyl interaction

Methodology Applied
Scientific EffectHydrogen bonding:

Implementation Method 2

excellent mechanical strength and adhesive strength due to hydrogen bonding and galloyl interaction

Methodology Applied
Scientific EffectGalloyl interaction:

Data Source

PatentUS20250361429A1Adhesive film, adhesive member comprising the same and method for bonding using the same
Publication Date: 2025.11.27 IND ACADEMIC COOP FOUND YONSEI UNIV
  • US20250361429A1 patent drawing
  • US20250361429A1 patent drawing
  • US20250361429A1 patent drawing

AI summary

Disclosed are an adhesive film which may be applied to not only rigid electronic devices but also soft electronic devices by having excellent mechanical strength and adhesive strength due to hydrogen bonding and galloyl interaction, as well as high transparency, coating uniformity, and flexibility, an adhesive member including the same, and a bonding method using the same.