Multilayer Polyphenylene Sheet Adhesive-Free Lamination

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Solution Overview

Problem

Poly(phenylene ether) based films used in electrical insulation applications face issues with hydrolysis of the adhesive layer due to high humidity and temperature exposure, and the lamination process adds cost to production, necessitating a multilayer sheet without an adhesive layer that maintains mechanical properties.

Innovation Solution

A multilayer sheet comprising a core layer with polyphenylene, polystyrene, and a hydrogenated block copolymer, and cap layers made of polypropylene, which eliminates the need for an adhesive layer by enhancing interlayer bonding strength and providing mechanical stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If an adhesive layer is used to bond polyphenylene ether layer and ultraviolet light shielding layer, then the layers can be laminated together, but the adhesive layer undergoes hydrolysis after long-term exposure to high humidity and high temperatures

Engineering Contradiction:
Improvelong-term stabilityVSAvoidhydrolysis of adhesive layer
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent removes the adhesive layer entirely from the multilayer structure. By directly laminating the polyphenylene ether layer with the ultraviolet light shielding layer without an intermediate adhesive layer, the source of hydrolysis is eliminated, thereby improving long-term stability under high humidity and temperature conditions.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent merges the bonding function into the lamination process itself, using direct thermal lamination to bond layers together without requiring a separate adhesive material. This integration eliminates the adhesive layer that would otherwise be susceptible to hydrolysis.

Inventive Principle:
Principle #5Merging (Combining)

2Ease of manufacture

If an adhesive layer is used to bond layers together, then the multilayer structure can be formed, but the lamination process adds additional cost to production

Engineering Contradiction:
Improvelayer bonding capabilityVSAvoidproduction process complexity
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The patent extracts and removes the adhesive layer from the multilayer construction, thereby eliminating the need for separate adhesive application and bonding processes. This simplifies the overall production process and reduces manufacturing costs while maintaining layer bonding capability through direct thermal lamination.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent combines the layer bonding function directly into the lamination process, eliminating the need for a separate adhesive application step. This integration reduces process complexity and manufacturing costs while achieving the same structural outcome.

Inventive Principle:
Principle #5Merging (Combining)

3Strength

If polyphenylene ether based films are used for electrical insulation, then desirable mechanical properties are achieved, but compatibility issues arise with ultraviolet light shielding layers

Engineering Contradiction:
Improvemechanical propertiesVSAvoidlayer compatibility
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The patent removes the incompatible adhesive layer that acted as an interface between the polyphenylene ether layer and ultraviolet light shielding layer. By eliminating this intermediate layer, the patent achieves direct compatibility between the functional layers while preserving the mechanical properties of the polyphenylene ether base film.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a multilayer sheet with improved hydrothermal resistance and dimensional stability, reducing the risk of hydrolysis and eliminating the need for an adhesive layer, thus lowering production costs while maintaining mechanical properties.

Implementation Method 1

enhancing interlayer bonding strength

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

co-extruding a core layer and a first cap layer

Methodology Applied
Scientific EffectExtrusion: Extrusion

Data Source

PatentUS11806970B2Multilayer sheets including polyphenylene and polypropylene and methods of making the same (as amended)
Publication Date: 2023.11.07 SABIC GLOBAL TECHNOLOGIES BV
  • US11806970B2 patent drawing
  • US11806970B2 patent drawing
  • US11806970B2 patent drawing

AI summary

A multilayer sheet includes a core layer including a composition including about (60) to about (90) weight percent of polyphenylene, about (0) to about (20) weight percent of polystyrene, about (10) to about (20) weight percent of a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, and optionally, a flame retardant additive; and a first cap layer disposed on a surface of the core layer, wherein the first cap layer includes polypropylene.